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Russian Journal of General Chemistry

, Volume 89, Issue 8, pp 1560–1563 | Cite as

Decomposition of Benzoyl Peroxide in the Presence of Ferrocene

  • N. M. Andriyashina
  • S. A. GrabovskiiEmail author
  • N. N. Kabal’nova
Article

Abstract

Decomposition of benzoyl peroxide in the presence of ferrocene has been shown to proceed simultaneously via several pathways—thermal decomposition, the decomposition catalyzed by iron ions, and the reaction with ferrocene with the formation of ferrocenium radical-cation.

Keywords

benzoyl peroxide ferrocene thermal stability reaction kinetics 

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Notes

Funding

This study was performed in the scope of the research topic of UIC RAS, no. AAAA-A17-117011910035-5. The authors acknowledge the Center for Collective Usage “Chemistry” of UIC RAS for providing the opportunity to carry out UV, NMR and ESR spectroscopic studies.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • N. M. Andriyashina
    • 1
  • S. A. Grabovskii
    • 1
    Email author
  • N. N. Kabal’nova
    • 1
  1. 1.Federal State Ufa Institute of ChemistryRussian Academy of SciencesUfaRussia

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