Russian Journal of General Chemistry

, Volume 89, Issue 8, pp 1554–1559 | Cite as

Alkylation of Phenols with tert-Butanol Catalyzed by H-Form of Y Zeolites with a Hierarchical Porous Structure

  • A. R. BayguzinaEmail author
  • R. A. Makhiyanova
  • A. N. Khazipova
  • R. I. Khusnutdinov


tert-Butyl-substituted phenols have been synthesized via the reaction of phenol, o-, m-, and p-cresols with tert-butanol under the action of CBr4-promoted Y-zeolites in the H-form with a hierarchical porous structure.


phenol tert-butanol tert-butylphenols 2,4-di-tert-butylphenol cresol zeolite HY 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.



This study was financially supported by the Russian Foundation for Basic Research (project 17-43-020155r_a) and performed in the scope of the State Task of the Ministry of Education and Science of the Russian Federation (no. AAAA-A19-119022290009-3). Structural study of the obtained compounds was performed using the equipment of Agidel Regional Center for Collective Usage.


  1. 1.
    Terekhov, A.V, Zanaveskin, L.N., and Khadzhiev, S.N., Petroleum Chem., 2017, vol. 57, no. 4, p. 714. doi CrossRefGoogle Scholar
  2. 2.
    Selvam, P., Krishna, N.V., and Sakthivel, A., Adv. Porous. Mater., 2013, no. 3, p. 239. doi
  3. 3.
    Song, K., Guan, J., Wu, S., Yang, Y., Liu, B., and Kan, Q., Catal. Lett., 2008, vol. 126, no. 3, p. 333. doi CrossRefGoogle Scholar
  4. 4.
    Harmer, M.A. and Sun, Q., Appl. Catal. (A), 2001, vol. 221, p. 45. doi CrossRefGoogle Scholar
  5. 5.
    Krishnan, A.V., Keka, O., and Pradhan, N.C., Org. Proc. Res. Dev., 2002, vol. 6, p. 132. doi CrossRefGoogle Scholar
  6. 6.
    Dumitriu, E. and Hulea, V., J. Catal., 2003, vol. 218, no. 2, p. 249. doi CrossRefGoogle Scholar
  7. 7.
    Travkina, O.S., Agliullin, M.R., Filippova, N.A., Khazipova, A.N., Danilova, I.G., Grigoreva, N.G., Narender Nama, Pavlova, M.L., and Kutepov, B.I., RSC Adv., 2017, vol. 52, p. 32581. doi CrossRefGoogle Scholar
  8. 8.
    Tantseva, A.A., Khazipova, A.N., Garieva, G.F., and Kutepov, B.I., Russ. J. Appl. Chem., 2010, vol. 83, no. 12, p. 2100. doi CrossRefGoogle Scholar
  9. 9.
    Bayer, H.K., Dealumination Techniques for Zeolites. Molecular Sieves, Berlin: Springer-Verlag, 2002, vol. 3, p. 203.Google Scholar
  10. 10.
    Lutz, W., Adv. Mat. Sci. Eng., 2014, p. 1. doi
  11. 11.
    Zeolites in Catalysis: Properties and Applications, Čejka, J., Morris, R.E., and Nachtigall, P., Eds., London: Royal Society of Chemistry, 2017, p. 310.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. R. Bayguzina
    • 1
    • 2
    Email author
  • R. A. Makhiyanova
    • 2
  • A. N. Khazipova
    • 1
  • R. I. Khusnutdinov
    • 1
    • 2
  1. 1.Institute of Petrochemistry and CatalysysRussian Academy of SciencesUfaRussia
  2. 2.Ufa State Petroleum Technological UniversityUfaRussia

Personalised recommendations