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Russian Journal of General Chemistry

, Volume 89, Issue 7, pp 1447–1450 | Cite as

Mechanically Activated Solid-Phase Reaction of Copper(I) Chloride with Sodium β-Diketonates: Formation of Metallic Copper Nanoparticles

  • V. D. MakhaevEmail author
  • L. A. Petrova
  • Yu. M. Shulga
Article
  • 2 Downloads

Abstract

Solid-phase reaction of copper(I) chloride with sodium β-diketonates under mechanical activation in a vibration ball mill involves disproportionation of CuCl with the formation of the corresponding copper(II) β-diketonate and highly reactive X-ray amorphous metallic copper nanoparticles. The effect of reaction conditions on the process and some properties of the activated mixtures have been studied.

Keywords

mechanical activation solid-phase synthesis copper(II) β-diketonates nanomaterials nanosized copper 

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Notes

Funding

This study was financially supported by the Ministry of Education and Science within the framework of State contract (State registration no. 01201361869)..

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. D. Makhaev
    • 1
    Email author
  • L. A. Petrova
    • 1
  • Yu. M. Shulga
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia

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