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Russian Journal of General Chemistry

, Volume 89, Issue 6, pp 1102–1114 | Cite as

Design of Supramolecular Cluster Compounds of Copper Subgroup Metals Based on Polydentate Phosphine Ligands

  • E. V. GrachovaEmail author
Article

Abstract

Principles and examples of assembling heteroleptic supramolecular cluster compounds of copper subgroup metals based on polydentate phosphine ligands of various topologies are considered. The choice of an organic linker between phosphorus atoms allows one to control the formation of three-dimensional aggregates with a regular architecture, whereas the choice of alkynyl ligands determines their luminescent properties.

Keywords

copper subgroup metals metallophilic and aurophilic interactions phosphine ligands cluster compounds cage molecules molecular emitters 

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.St. Petersburg State UniversitySt. PetersburgRussia

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