Advertisement

Russian Journal of General Chemistry

, Volume 89, Issue 2, pp 261–265 | Cite as

Zinc(II) Complexes with Tetrafluoroterephthalic and Octafluorobiphenyl-4,4′-dicarboxylic Acid Anions and 1,10-Phenanthroline

  • S. V. Larionov
  • M. I. Rakhmanova
  • L. A. GlinskayaEmail author
  • D. Yu. Naumov
  • A. S. Vinogradov
  • V. M. Karpov
  • V. E. Platonov
  • V. P. Fadeeva
Article
  • 13 Downloads

Abstract

Zinc(II) complexes with 1,10-phenanthroline and tetrafluoroterephthalate and octafluorobiphenyl 4,4′-dicarboxylate anions have been synthesized. According to the IR spectral data, the complexation involves coordination of the metal ion to the nitrogen atoms of phenanthroline and carboxylate oxygen atom of the acid anion. The complexes show photoluminescence in the visible region of the spectrum. The structure of the complex salt [Zn(H2O)6][Zn(H2O)4(L2)2] · H2O, where L2 is octafluorobiphenyl-4,4′-dicarboxylate anion (monodentate ligand), has been determined by X-ray analysis.

Keywords

perfluorocarboxylic acids zinc complexes photoluminescence 1,10-phenanthroline coordination polymers 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Batten, S.R., Neville, S.M., and Turner, D.R., Coordination Polymers. Design, Analysis and Application, Cambridge UK: Roy. Soc. Chem., 2009.Google Scholar
  2. 2.
    Allendorf, M.D., Bauer, C.A., Bhakta, R.K., and Houk, R.J.T., Chem. Soc. Rev., 2009, vol. 38, p. 1330. doi 10.1039/b80235mCrossRefGoogle Scholar
  3. 3.
    Chun, H., Dybtsev, D.N., Kim, H., and Kim, K., Chem. Eur. J., 2005, vol. 11, p. 3521. doi 10.1002/chem.200401201CrossRefGoogle Scholar
  4. 4.
    Seidel, C., Ahlers, R., and Rushewitz, U., Cryst. Growth Des., 2011, vol. 11, p. 5053. doi 10.1021/cg200974hCrossRefGoogle Scholar
  5. 5.
    Hulvey, Z., Furman, J.D., Turner, S.A., Tang, M., and Cheetham, A.K., Cryst. Growth Des., 2010, vol. 10, p. 2041. doi 10.1021/cg100121nCrossRefGoogle Scholar
  6. 6.
    Hulvey, Z., Melot, B.C., and Cheetham, A.K., Inorg. Chem., 2010, vol. 49, no. 10, p. 4594. doi 10.1021/ic100164kCrossRefGoogle Scholar
  7. 7.
    Hulvey, Z., Ayala, E., and Cheetham, A.K., Z. Anorg. Allg. Chem., 2009, vol. 635, no. 12, p. 1773. doi 10.1002/zaac.200900312CrossRefGoogle Scholar
  8. 8.
    Hulvey, Z., Sava, D.A., Eckert, J., and Cheetham, A.K., Inorg. Chem., 2011, vol. 50, no. 2, p. 403. doi 10.1021/ic101153cCrossRefGoogle Scholar
  9. 9.
    Larionov, S.V., Myachina, L.I., Klevtsova, R.F., Glinskaya, L.A., Kurat’eva, N.V., Uskov, E.M., Karpov, V.M., Platonov, V.E., and Fadeeva, V.P., Russ. J. Coord. Chem., 2011, vol. 37, no. 9, p. 650. doi 10.1134/S1070328411090041CrossRefGoogle Scholar
  10. 10.
    Lan, A., Li, K., Wu, H., Olson, D.H., Emge, T.J., Ki, W., Hong, M., and Li, J., Angew. Chem., Int. Ed., 2009, vol. 48, no. 13, p. 2334. doi 10.1002/anie.200804853CrossRefGoogle Scholar
  11. 11.
    Larionov, S.V., Myachina, L.I., Sheludyakova, L.A., Korol’kov, I.V., Rakhmanova, M.I., Plyusnin, P.E., Vinogradov, A.S., Karpov, V.M., Platonov, V.E., and Fadeeva, V.P., Russ. J. Gen. Chem., 2015, vol. 85, no. 7, p. 1617. doi 10.1134/S1070363215070075CrossRefGoogle Scholar
  12. 12.
    Cheplakova, A.M., Kovalenko, K.A., Samsonenko, D.G., Lazarenko, V.A., Khrustalev, V.N., Vinogradov, A.S., Karpov, V.M., Platonov, V.E., and Fedin, V.P., Dalton Trans., 2018, vol. 47, no. 10, p. 3272. doi 10.1039/c7dt04566bCrossRefGoogle Scholar
  13. 13.
    Larionov, S.V., Myachina, L.I., Sheludyakova, L.A., Korol’kov, I.V., Antonova, O.V., Karpov, V.M., Platonov, V.E., and Fadeeva, V.P., Russ. J. Gen. Chem., 2014, vol. 84, no. 6, p. 1193. doi 10.1134/S107036321406022XCrossRefGoogle Scholar
  14. 14.
    Sintezy fluoroorganicheskikh soedinenii (Syntheses of Organofluorine Compounds), Knunyants, I.L., Yakobson, G.G., Eds., Moscow: Khimiya. 1973, p. 173.Google Scholar
  15. 15.
    Larionov, S.V., Kirichenko, V.N., Rastorguev, A.A., Belyi, V.I., Sheludyakova, L.A., Fadeeva, V.P., Karpov, V.M., Platonov, V.E., Batrachenko, N.I., and Lisoivan, V.I., Koord. Khim., 1997, vol. 23, no. 6, p. 465.Google Scholar
  16. 16.
    Sheldrick, G.M., Acta Crystallogr., Sect. C, 2015, vol. 71, p. 3. doi 10.1107/S2053229614024218CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • S. V. Larionov
    • 1
    • 2
  • M. I. Rakhmanova
    • 1
  • L. A. Glinskaya
    • 1
    Email author
  • D. Yu. Naumov
    • 1
    • 2
  • A. S. Vinogradov
    • 3
  • V. M. Karpov
    • 3
  • V. E. Platonov
    • 3
  • V. P. Fadeeva
    • 2
    • 3
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk National Research State UniversityNovosibirskRussia
  3. 3.Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia

Personalised recommendations