Advertisement

Russian Journal of Coordination Chemistry

, Volume 45, Issue 11, pp 809–816 | Cite as

Synthesis, Characterization and Crystal Structures of Oxidovanadium(V) and Dioxidomolybdenum(VI) Complexes Derived from 2-bromo-N'-(2-hydroxy-3-methoxybenzylidene)benzohydrazide with Catalytic Property

  • H. Y. LiuEmail author
  • X. L. Zou
  • H. H. Yang
  • Y. F. Ye
  • L. J. Yang
Article
  • 6 Downloads

Abstract

A hydrazone compound 2-bromo-N'-(2-hydroxy-3-methoxybenzylidene)benzohydrazide (H2L) was prepared and characterized by IR, UV-Vis and NMR spectra. Based on the hydrazone compound, a new oxidovanadium(V) and a new dioxidomolybdenum(VI) complexes, [VO(L)(OEt)(EtOH)] (I) and [MoO2(L)(OH2)] (II), were prepared and characterized by IR, UV-Vis, NMR spectra, and single crystal X-ray diffraction (CIF files nos. 1866755 (I) and 1866756 (II)). Complex I crystallizes as the monoclinic space group P21/c with unit cell dimensions a = 12.8733(12), b = 13.5088(13), c = 11.9262(11) Å, β = 91.765(2)°, V = 2073.0(3) Å3, Z = 4, R1 = 0.0524, wR2 = 0.1329, GOOF = 1.245. Complex II crystallizes as the monoclinic space group P21/c with unit cell dimensions a = 8.1140(9), b = 16.2975(19), c = 13.4318(15) Å, β = 106.456(2)°, V = 1703.4(3) Å3, Z = 4, R1 = 0.0296, wR2 = 0.0728, GOOF = 1.046. X-ray analysis indicates that the complexes are mononuclear species with the metal atoms in octahedral coordination. The complexes were studied for catalytic oxidation property on some olefins with tert-butyl hydrogen peroxide as oxidant.

Keywords:

hydrazone vanadium complex molybdenum complex crystal structure catalytic property 

Notes

ACKNOWLEDGMENTS

The national high technology research and development program (863 program, 2012AA020304). Guangdong province science and technology plan program (no. 2012145). Guangdong province science and technology plan program (no. 2015110).

REFERENCES

  1. 1.
    Gryca, I., Czerwinska, K., Machura, B., et al., Inorg. Chem., 2018, vol. 57, no. 4, p. 1824.CrossRefGoogle Scholar
  2. 2.
    Fomenko, I.S., Gushchin, A.L., Shulpina, L.S., et al., New J. Chem., 2018, vol. 42, no. 19, p. 16200.CrossRefGoogle Scholar
  3. 3.
    Langeslay, R.R., Kaphan, D.M., Marshall, C.L., et al., Chem. Rev.  https://doi.org/10.1021/acs.chemrev.8b00245
  4. 4.
    Peng, D.-L., Transit. Met. Chem., 2016, vol. 41, no. 8, p. 843.CrossRefGoogle Scholar
  5. 5.
    Sutradhar, M., Martins, L.M.D.R.S., Carabineiro, S.A.C., et al., ChemCatChem, 2016, vol. 8, no. 13, p. 2254.CrossRefGoogle Scholar
  6. 6.
    Zhu, X.W., Russ. J. Coord. Chem., 2018, vol. 44, no. 7, p. 421.  https://doi.org/10.1134/S1070328418070084 CrossRefGoogle Scholar
  7. 7.
    Maurya, M.R., Haldar, C., Kumar, A., et al., Dalton Trans., 2013, vol. 42, no. 33, p. 11941.CrossRefGoogle Scholar
  8. 8.
    Peng, D.L., Russ. J. Coord. Chem., 2017, vol. 43, no. 6, p. 404.  https://doi.org/10.1134/S1070328417060045 CrossRefGoogle Scholar
  9. 9.
    Gazi, S., Ng, W.K.H., Ganguly, R., et al., Chem. Sci., 2015, vol. 6, no. 12, p. 7130.CrossRefGoogle Scholar
  10. 10.
    Peng, D.L., Russ. J. Coord. Chem., 2017, vol. 43, no. 3, p. 189.  https://doi.org/10.1134/S1070328417030058 CrossRefGoogle Scholar
  11. 11.
    Sheikhsoaie, I., Rezaeffard, A., Monadi, N., et al., Polyhedron, 2009, vol. 28, no. 4, p. 733.CrossRefGoogle Scholar
  12. 12.
    Peng, D.-L., J. Struct. Chem., 2018, vol. 59, no. 3, p. 589.CrossRefGoogle Scholar
  13. 13.
    Rayati, S., Rafiee, N., and Wojtczak, A., Inorg. Chim. Acta, 2012, vol. 386, p. 27.CrossRefGoogle Scholar
  14. 14.
    Liu, H.-Y., Russ. J. Coord. Chem., 2013, vol. 39, no. 8, p. 583.  https://doi.org/10.1134/S1070328413070063 CrossRefGoogle Scholar
  15. 15.
    Liu, H.Y., Li, G.W., Li, Z.L., et al., Russ. J. Coord. Chem., 2011, vol. 37, no. 9, p. 668.  https://doi.org/10.1134/S1070328411080070 CrossRefGoogle Scholar
  16. 16.
    Liu, H.-Y., J. Struct. Chem., 2014, vol. 55, no. 1, p. 134.CrossRefGoogle Scholar
  17. 17.
    Liu, H.Y., Zhang, L.Q., and Lv, J.L., Russ. J. Coord. Chem., 2015, vol. 41, no. 7, p. 451.  https://doi.org/10.1134/S1070328415070052 CrossRefGoogle Scholar
  18. 18.
    Liu, H.Y., Yang, H.H., Diao, Y.X., et al., Russ. J. Coord. Chem., 2018, vol. 44, no. 9, p. 572.  https://doi.org/10.1134/S1070328418090063 CrossRefGoogle Scholar
  19. 19.
    SMART (version 5.625) and SAINT (version 6.01), Madison: Bruker AXS Inc., 2007.Google Scholar
  20. 20.
    Sheldrick, G.M., SADABS, Program for Empirical Absorption Correction of Area Detector, Göttingen: Univ. of Göttingen, 1996.Google Scholar
  21. 21.
    Sheldrick, G.M., SHELXTL (version 5.1), Software Reference Manual, Madison: Bruker AXS, Inc., 1997.Google Scholar
  22. 22.
    Li, L., Lv, K.W., Li, Y.T., et al., Chinese J. Inorg. Chem., 2017, vol. 33, no. 5, p. 905.Google Scholar
  23. 23.
    Sarkar, A. and Pal, S., Polyhedron, 2007, vol. 26, no. 6, p. 1205.CrossRefGoogle Scholar
  24. 24.
    Monfared, H.H., Alavi, S., Bikas, R., et al., Polyhedron, 2010, vol. 29, no. 18, p. 3355.CrossRefGoogle Scholar
  25. 25.
    Zhang, X.-T., Zhan, X.-P., Wu, D.-M., et al., Chinese J. Struct. Chem., 2002, vol. 21, no. 8, p. 629.Google Scholar
  26. 26.
    Aravindakshan, A.A., Joseph, B., Kala, U.L., et al., Polyhedron, 2017, vol. 123, p. 206.CrossRefGoogle Scholar
  27. 27.
    Shit, M., Maity, S., Bera, S., et al., New J. Chem., 2016, vol. 40, no. 12, p. 10305.CrossRefGoogle Scholar
  28. 28.
    Yousef Ebrahimipour, S., Sheikhshoaie, I., Simpson, J., et al., New J. Chem., 2016, vol. 40, no. 3, p. 2401.CrossRefGoogle Scholar
  29. 29.
    Maurya, M.R., Rana, L., and Avecilla, F., Polyhedron, 2017, vol. 126, p. 60.CrossRefGoogle Scholar
  30. 30.
    Bikas, R., Lippolis, V., Noshiranzadeh, N., et al., Eur. J. Inorg. Chem., 2017, no. 6, p. 999.Google Scholar
  31. 31.
    Cui, Y.-M., Qiao, L., Li, Y., et al., Transition Met. Chem., 2017, vol. 42, no. 1, p. 51.Google Scholar
  32. 32.
    Monfared, H.H., Bikas, R., and Mayer, P., Inorg. Chim. Acta, 2010, vol. 363, no. 11, p. 2574.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • H. Y. Liu
    • 1
    • 2
    Email author
  • X. L. Zou
    • 1
    • 2
  • H. H. Yang
    • 1
    • 2
  • Y. F. Ye
    • 1
    • 2
  • L. J. Yang
    • 1
    • 2
  1. 1.School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical UniversityZhongshanP.R. China
  2. 2.Guangdong Cosmetics Engineering and Technology Research CenterZhongshanP.R. China

Personalised recommendations