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Russian Journal of Coordination Chemistry

, Volume 45, Issue 7, pp 524–531 | Cite as

Synthesis, Structures, and Properties of Two Coordination Polymers with Chelating Carboxylic and Triazolyl Derivatives

  • Y. F. WangEmail author
  • J. J. Wei
  • M. M. Zhang
  • L. Y. WangEmail author
Article
  • 5 Downloads

Abstract

Two coordination polymers, [Zn(Btec)0.5(H2L)]n (I) and [Cd0.5(Tp)0.5(H2L')(H2O)]nnH2O (II) (H2L = 3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1,2,4-triazole; H4Btec = 1,2,4,5-benzenetetracarboxylic acid; H2L' = 3-(1H-pyrazol-4-yl)-5-(pyridin-3-yl)-1,2,4-triazole; H2Tp = terephthalic acid), have been synthesized under hydrothermal conditions. The title compounds were structurally characterized by elemental analysis, single crystal X-ray diffraction analysis, infrared spectra. Compounds I and II crystallize in the orthorhombic and triclinic, space group Pbca and P¯1, respectively. Compound I displays a two-dimensional plane structure, those are connected by N···H···O hydrogen bonds to generate 3D frameworks. Compound II is constructed a 1D chain structure by Tp2− ligands, which are connected into 2D structure by the hydrogen bonds. In addition, the fluorescent property of I has been studied in the solid state at room temperature. The thermal analysis of I has also been investigated.

Keywords:

coordination polymers structure fluorescent property 

Notes

FUNDING

This work was supported by the National Natural Science Foundation of China (no. 21671114) and the Science and Technology Project of Henan Province (no. 162106000025).

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.College of Chemistry and Chemical Engineering, Luoyang Normal UniversityLuoyangP.R. China
  2. 2.Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal UniversityLuoyangP.R. China
  3. 3.College of Chemistry and Pharmaceutical Engineering, Nanyang Normal UniversityNanyangP.R. China

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