Russian Journal of Coordination Chemistry

, Volume 45, Issue 7, pp 478–483 | Cite as

Synthesis and Crystal and Molecular Structures of Nickel(II) and Copper(II) 1,5-Napthalenedisulfonate Complexes with Nicotinamide

  • V. S. SergienkoEmail author
  • T. V. Koksharova
  • M. D. Surazhskaya
  • T. S. Skakun
  • O. A. Egorova


Coordination compounds of nickel(II) and copper(II) 1,5-naphthalenedisulfonates with nicotinamides, [Ni(L)2(H2O)4](Nds) · 3H2O (I) and [Cu(L)2(H2O)4](Nds) (II) (L = nicotinamide, NC5H4C(O)NH2, Nds2 = doubly deprotonated 1,5-naphthaledisulfonate anion, \({{{\text{C}}}_{{{\text{1}}0}}}{{{\text{H}}}_{{\text{6}}}}({\text{S}}{{{\text{O}}}_{{\text{3}}}})_{{\text{2}}}^{{{\text{2}}-}}\)), were synthesized and studied by IR and diffuse reflectance spectroscopy. The crystal structures of I and II were determined by X-ray diffraction (CIF files CCDC nos. 1863367 (I) and 1863368 (II)). In both structures, the Ni and Cu atoms are coordinated by two nitrogen atoms of two monodentate L ligands and by four oxygen atoms of water molecules. The coordination polyhedron of Ni in I is a slightly distorted octahedron and that of Cu in II is a tetragonal (4 + 2) bipyramid extended due to the Jahn–Teller effect, with the O(H2O) atoms in the axial positions. The [M(L)2(H2O)4]2+ complex cations, the Nds2– anions, and water molecules of crystallization in II are combined by a branched network of hydrogen bonds.


synthesis crystal structure X-ray diffraction nickel and copper complex with nicotinamide 1,5-naphthalenedisulfonate anions 



X-ray diffraction analysis was performed at the Center for Collective Use of Physical Investigation Methods, Kurnakov Institute of General and Inorganic Chemistry, RAS.


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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. S. Sergienko
    • 1
    • 2
    Email author
  • T. V. Koksharova
    • 3
  • M. D. Surazhskaya
    • 1
  • T. S. Skakun
    • 3
  • O. A. Egorova
    • 4
  1. 1.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia
  2. 2.All-Russia Institute for Scientific and Technical InformationMoscowRussia
  3. 3.Odessa I.I. Mechnikov National UniversityOdessaUkraine
  4. 4.Peoples’ Friendship University of RussiaMoscowRussia

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