Advertisement

Russian Journal of Coordination Chemistry

, Volume 45, Issue 7, pp 478–483 | Cite as

Synthesis and Crystal and Molecular Structures of Nickel(II) and Copper(II) 1,5-Napthalenedisulfonate Complexes with Nicotinamide

  • V. S. SergienkoEmail author
  • T. V. Koksharova
  • M. D. Surazhskaya
  • T. S. Skakun
  • O. A. Egorova
Article
  • 1 Downloads

Abstract

Coordination compounds of nickel(II) and copper(II) 1,5-naphthalenedisulfonates with nicotinamides, [Ni(L)2(H2O)4](Nds) · 3H2O (I) and [Cu(L)2(H2O)4](Nds) (II) (L = nicotinamide, NC5H4C(O)NH2, Nds2 = doubly deprotonated 1,5-naphthaledisulfonate anion, \({{{\text{C}}}_{{{\text{1}}0}}}{{{\text{H}}}_{{\text{6}}}}({\text{S}}{{{\text{O}}}_{{\text{3}}}})_{{\text{2}}}^{{{\text{2}}-}}\)), were synthesized and studied by IR and diffuse reflectance spectroscopy. The crystal structures of I and II were determined by X-ray diffraction (CIF files CCDC nos. 1863367 (I) and 1863368 (II)). In both structures, the Ni and Cu atoms are coordinated by two nitrogen atoms of two monodentate L ligands and by four oxygen atoms of water molecules. The coordination polyhedron of Ni in I is a slightly distorted octahedron and that of Cu in II is a tetragonal (4 + 2) bipyramid extended due to the Jahn–Teller effect, with the O(H2O) atoms in the axial positions. The [M(L)2(H2O)4]2+ complex cations, the Nds2– anions, and water molecules of crystallization in II are combined by a branched network of hydrogen bonds.

Keywords:

synthesis crystal structure X-ray diffraction nickel and copper complex with nicotinamide 1,5-naphthalenedisulfonate anions 

Notes

ACKNOWLEDGMENTS

X-ray diffraction analysis was performed at the Center for Collective Use of Physical Investigation Methods, Kurnakov Institute of General and Inorganic Chemistry, RAS.

REFERENCES

  1. 1.
    Antsyshkina, A.S., Porai-Koshits, M.A., Gandlovich, M., et al., Koord. Khim., 1979, vol. 5, no. 11, p. 1716.Google Scholar
  2. 2.
    Antsyshkina, A.S., Sadikov, G.G., Koksharova, T.V., et al., Russ. J. Inorg. Chem., 2006, vol. 51, no. 10, p. 1571.  https://doi.org/10.1134/S003602360610010X CrossRefGoogle Scholar
  3. 3.
    Sadikov, G.G., Koksharova, T.V., Antsyshkina, A.S., et al., Cryst. Rep., 2008, vol. 53, no. 4, p. 631.  https://doi.org/10.1134/S1063774508040135 CrossRefGoogle Scholar
  4. 4.
    Matsaberidze, M.M., Batsanov, A.S., Gerr, R.G., et al., Koord. Khim., 1985, vol. 11. no. 3, p. 411.Google Scholar
  5. 5.
    Antsyshkina, A.S., Sadikov, G.G., Koksharova, T.V., et al., Russ. J. Inorg. Chem., 2009, vol. 54, no. 8, p. 1310.  https://doi.org/10.1134/S003602360908021X CrossRefGoogle Scholar
  6. 6.
    Sadikov, G.G., Antsyshkina, A.S., Koksharova, T.V., et al., Cryst. Rep., 2007, vol. 52, no. 5, p. 819.  https://doi.org/10.1134/S1063774507050112 CrossRefGoogle Scholar
  7. 7.
    Azizov, T.A., Sharipov, Kh.T., Parpiev, N.A., et al., Zh. Neorg. Khim., 1991, vol. 36. no. 7, p. 1722.Google Scholar
  8. 8.
    Zhaoxun Lian, Ning Zhao, and Ping Liu, Z. Kristallogr. NCS, 2010, vol. 225, no. 2, p. 371.CrossRefGoogle Scholar
  9. 9.
    Chen Cai-Hong, Cai Ji-Wen, Feng Xiao-Long, and Chen Xiao-Ming, Chinese J. Inorg. Chem., 2002, vol. 18, no. 7, p. 659.Google Scholar
  10. 10.
    Shabilalov, A.A., Borisova, N.N., and Azizov, M.A., Koord. Khim., 1987, vol. 13, no. 9, p. 1227.Google Scholar
  11. 11.
    Tsivadze, A.Yu., Tsintsadze, G.V., Kharitonov, Yu.Ya., and Gverdtsiteli, L.V., Zh. Neorg. Khim., 1978, vol. 23, no. 2, p. 447.Google Scholar
  12. 12.
    Tsintsadze, G.V., Shavtvaladze, M.V., and Tsivadze, A.Yu., Koord. Khim., 1990, vol. 16, no. 12, p. 1666.Google Scholar
  13. 13.
    Kukushkin, Yu.N., Khimiya koordinatsionnykh soedinenii (Chemistry of Coordination Compounds), Moscow: Vysshaya Shkola , 1985.Google Scholar
  14. 14.
    Jiwen Cai, Cai-Hong Chen, Cheng-Zhu Liao, et al., Dalton Trans., 2001, no. 7, p. 1137.Google Scholar
  15. 15.
    Jiwen Cai, Cai-Hong Chen, Xiao-Long Feng, et al., Dalton Trans., 2001, no. 16, p. 2370.Google Scholar
  16. 16.
    Perles, J., Snejko, N., Iglesias, M., et al., J. Mater. Chem., 2009, vol. 19, no. 36, p. 6504.CrossRefGoogle Scholar
  17. 17.
    Di Sun, Na Zhang, Zhan-Hua Wei, et al., J. Mol. Struct., 2010, vol. 981. nos. 1−3, p. 80.CrossRefGoogle Scholar
  18. 18.
    Di Sun, Fu-Jing Liu, Hong-Jun Hao, et al., CrystEngComm, 2011, vol. 13, no. 19, p. 5661.CrossRefGoogle Scholar
  19. 19.
    Wang Shuang, Zhang Renchun, Wang Junjie, et al., Chem. Res. Chinese Univ., 2014, vol. 30, no. 1, p. 9.Google Scholar
  20. 20.
    Lever, A., Inorganic Electronic Spectroscopy, New York: Elesvier, 1984, vol. 2.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. S. Sergienko
    • 1
    • 2
    Email author
  • T. V. Koksharova
    • 3
  • M. D. Surazhskaya
    • 1
  • T. S. Skakun
    • 3
  • O. A. Egorova
    • 4
  1. 1.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia
  2. 2.All-Russia Institute for Scientific and Technical InformationMoscowRussia
  3. 3.Odessa I.I. Mechnikov National UniversityOdessaUkraine
  4. 4.Peoples’ Friendship University of RussiaMoscowRussia

Personalised recommendations