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Russian Journal of Coordination Chemistry

, Volume 45, Issue 7, pp 517–523 | Cite as

Two Zinc(II)/Cadmium(II) Coordination Polymers Constructed by Semirigid Carboxylic Acid Ligand: Syntheses, Structures, and Photoluminescence Properties

  • Y. P. Li
  • F. Y. Ju
  • G. L. Li
  • L. Y. Xin
  • X. L. Li
  • G. Z. LiuEmail author
Article
  • 1 Downloads

Abstract

Two new coordination polymers {[Zn(HL)(HBpp)] · H2O}n (I) and [Cd(HL)(HBpe)]n (II) (H4L = 5-(2,3-dicarboxy phenoxy) isophthalic acid, Bpp = 1,3-bis(4-pyridyl)propane, Bpe = 1,2-bis(4-pyridyl)ethylene) were prepared and characterize by element analysis, powder XRD and single crystal X-ray diffraction (CCDC nos. 1836060 (I), 1844999 (II)). The single-crystal X-ray diffractions reveal that the complex I is a 2D carboxylate layer with the HBpp suspension arms, in which the zinc(II) is four-coordinated with a tetrahedral geometry. Compound II is a 1D Cd(II)-carboxylate chains, in which the cadmium(II) is seven-coordinated with a distorted pentagonal bipyramidal geometry. Complexes I and II are further extended into three-dimensional supramolecular framework via hydrogen bonds. The solid state luminescent properties of compounds I and II have been investigated.

Keywords:

mixed ligand coordination polymer fluorescence 

Notes

FUNDING

This work was supported by the National Natural Science Foundation of China (no. 21571093) and the Foundation of Science and Technology of Henan Province (no. 162102210304).

REFERENCES

  1. 1.
    Li, Y.L., Zhao, Y., Wang, P., et al., Inorg. Chem., 2016, vol. 55, p. 11821.CrossRefGoogle Scholar
  2. 2.
    Fei, H.H., Shin, J.W., Meng, Y.S., et al., J. Am. Chem. Soc., 2014, vol. 136, p. 4965.CrossRefGoogle Scholar
  3. 3.
    Zhang, X., Hu, Q., Xia, T.F., et al., ACS Appl. Mater. Interfaces, 2016, vol. 8, p. 32259.CrossRefGoogle Scholar
  4. 4.
    Wang, K., Du, L., Ma, Y., and Zhao, Q., Inorg. Chem. Commun., 2016, vol. 68, p. 45.CrossRefGoogle Scholar
  5. 5.
    Rojas, S., Carmona, F.J., Maldonado, C.R., et al., Inorg. Chem., 2016, vol. 55, p. 2650.CrossRefGoogle Scholar
  6. 6.
    Sadakiyo, M., Kasai, H., Kato, K., et al., J. Am. Chem. Soc., 2014, vol. 136, p. 1702.CrossRefGoogle Scholar
  7. 7.
    Li, T., Kozlowski, M.T., Doud, E.A., Blakely, M.N., et al., J. Am. Chem. Soc., 2013, vol. 135, p. 11688.CrossRefGoogle Scholar
  8. 8.
    Li, G.L., Liu, G.Z., Xin, L.Y., et al., J. Inorg. Organomet. Polym., 2015, vol. 25, p. 694.CrossRefGoogle Scholar
  9. 9.
    Ju, F.Y., Li, Y.P., Li, G.L., and Liu, G.Z., Chin. J. Struct. Chem., 2016, vol. 35, p. 404.Google Scholar
  10. 10.
    Furukawa, H., Cordova, K.E., O’Keeffe, M., et al., Science, 2013, vol. 341, p. 1230444.CrossRefGoogle Scholar
  11. 11.
    Mason, J.A., Veenstra, M., and Long, J.R., Chem. Sci., 2014, vol. 5, p. 32.CrossRefGoogle Scholar
  12. 12.
    Taylor, J.M., Dawson, K.W., and Shimizu, G.K., J. Am. Chem. Soc., 2013, vol. 135, p. 1193.CrossRefGoogle Scholar
  13. 13.
    Choi, M.H., Park, H.J., Hong, D.H., and Suh, M.P., Chemistry, 2013, vol. 19, p. 17432.CrossRefGoogle Scholar
  14. 14.
    He, Y.P., Tan, Y.X., and Zhang, J., Chem. Commun., 2013, vol. 49, p. 11323.CrossRefGoogle Scholar
  15. 15.
    Li, D.S., Wu, Y.P., Zhao, J., et al., Coord. Chem. Rev., 2014, vol. 261, p. 1.CrossRefGoogle Scholar
  16. 16.
    Ni, T., Xing, F., Shao, M., et al., Cryst. Growth Des., 2011, vol. 11, p. 2999.CrossRefGoogle Scholar
  17. 17.
    Xing, F., Bai, Y., He, X., et al., CrystEngComm, 2012, vol. 14, p. 4312.CrossRefGoogle Scholar
  18. 18.
    Wang, C.C., Zhang, Y.Q., Zhu, T., et al., Polyhedron, 2015, vol. 90, p. 58.CrossRefGoogle Scholar
  19. 19.
    Si, C.D., Hu, D.C., Fan, Y., et al., Cryst. Growth Des., 2015, vol. 15, p. 2419.CrossRefGoogle Scholar
  20. 20.
    Yang, D.L., Zhang, X., Yang, J.X., et al., Inorg. Chim. Acta, 2014, vol. 423, p. 62.CrossRefGoogle Scholar
  21. 21.
    Li, X.L., Liu, G.Z., Xin, L.Y., and Wang, L.Y., J. Solid State Chem., 2017, vol. 246, p. 252.CrossRefGoogle Scholar
  22. 22.
    Sheldrick, G.M., SHELXS-97, Program for Crystal Structure Solution, Göttigen: Univ. of Göttigen, 1997.Google Scholar
  23. 23.
    Guo, X.D., Zhu, G.S., Fang, Q.R., et al., Inorg. Chem., 2005, vol. 44, p. 3850.CrossRefGoogle Scholar
  24. 24.
    Tao, J., Tong, M.L., Shi, J.X., et al., Chem. Commun., 2000, vol. 20, p. 2043.CrossRefGoogle Scholar
  25. 25.
    Xin, L.Y., Liu, G.Z., Ma, L.F., and Wang, L.Y., J. Solid State Chem., 2014, vol. 206, p. 233.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • Y. P. Li
    • 1
    • 2
    • 3
  • F. Y. Ju
    • 1
    • 2
    • 3
  • G. L. Li
    • 1
    • 2
    • 3
  • L. Y. Xin
    • 1
    • 2
    • 3
  • X. L. Li
    • 1
    • 2
    • 3
  • G. Z. Liu
    • 1
    • 2
    • 3
    Email author
  1. 1.College of Chemistry and Chemical Engineering, Luoyang Normal UniversityLuoyangP.R. China
  2. 2.Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal UniversityLuoyangP.R. China
  3. 3.School of Food and Drug, Luoyang Normal UniversityLuoyangP.R. China

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