Advertisement

Russian Journal of Coordination Chemistry

, Volume 45, Issue 7, pp 473–477 | Cite as

Molecular Complex of Cadmium(II) Trifluoroacetate with Triphenylphosphine: Crystal Structure and Luminescence Properties

  • Yu. V. Kokunov
  • V. V. KovalevEmail author
  • Yu. E. Gorbunova
  • A. V. Churakov
  • S. A. Kozyukhin
Article
  • 1 Downloads

Abstract

Cadmium compound [Cd(CF3COO)2(Ph3P)2] is synthesized, and its crystal structure is determined. The crystals are monoclinic: space group C2/c, a = 20.318(4), b = 10.432(2), c = 18.661(4) Å, β = 104.18(1)°, V = 3834.8(13) Å3, Z = 4, ρcalcd = 1.495 g/cm3. The Cd atom arranged on the 2-fold crystallographic axis has a distorted octahedral coordination due to four oxygen atoms of crystallographically equivalent trifluoroacetate ligands and two phosphorus atoms of triphenylphosphine. Each fluorine atom of the trifluoroacetate groups is randomly disordered over three equally probable positions. The compound is luminescent.

Keywords:

cadmium trifluoroacetate triphenylphosphine structure luminescence 

Notes

FUNDING

This work was supported by the state task of the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) in the area of basic research.

REFERENCES

  1. 1.
    Grabtree, R.H., The Organometallic Chemistry of the Transition Metals, Willey, 2005.CrossRefGoogle Scholar
  2. 2.
    Bart, J., Levason, W., and Reid, G., Coord. Chem. Rev., 2014, vol. 260, p. 65.CrossRefGoogle Scholar
  3. 3.
    Parus, A., Wieszczycka, K., and Olszanowski, A., Hydrometallurgy, 2011, vol. 105, p. 284.CrossRefGoogle Scholar
  4. 4.
    Kessler, J.M., Reeder, J.H., Vac, R., et al., Magn. Reson. Chem., 1991, vol. 29, p. 94.CrossRefGoogle Scholar
  5. 5.
    Dakternieks, D., Hoskins, B., Rolls, C., and Tielink, E., Aust. J. Chem., 1986, vol. 39, p. 713.CrossRefGoogle Scholar
  6. 6.
    Cameron, A.F., Forrest, K.P., and Ferguson, G., J. Chem. Soc. A, 1971, p. 1286.Google Scholar
  7. 7.
    Bell, N.A., Dee, T.D., Goldstein, M., and Nowell, I.W., Inorg. Chim. Acta, 1980, vol. 38, p. 191.CrossRefGoogle Scholar
  8. 8.
    Zeng, D., Hampden-Smith, M.J., Alam, T.M., and Rheingold, A.L., Polyhedron, 1994, vol. 13, p. 2715.CrossRefGoogle Scholar
  9. 9.
    Darensbourg, D.J., Rainey, P., Larkins, D.L., and Reibenspies, H., Inorg. Chem., 2000, vol. 39, p. 473.CrossRefGoogle Scholar
  10. 10.
    Goel, R.G., Henry, W.P., Oliver, M.J., and Beauchamp, A.L., Inorg. Chem., 1981, vol. 20, p. 3924.CrossRefGoogle Scholar
  11. 11.
    Goel, R.G. and Jha, N.K., Can. J. Chem., 1981, vol. 59, p. 3267.CrossRefGoogle Scholar
  12. 12.
    Allman, T., Goel, R.G., Jha, N.K., and Beauchamp, A.L., Inorg. Chem., 1984, vol. 23, no. 7, p. 914.CrossRefGoogle Scholar
  13. 13.
    Sheldrick, G.M., SHELXS-97. Program for the Solution of Crystal Structures, Göttingen: Univ. of Göttingen, 1997.Google Scholar
  14. 14.
    Sheldrick, G.M., SHELXS-97. Program for the Refinement of Crystal Structures, Göttingen: Univ. of Göttingen, 1997.Google Scholar
  15. 15.
    King, C., Khan, M.N.I., Staples, R.J., and Facker, J.P., Inorg. Chem., 1992, vol. 31, p. 3236.CrossRefGoogle Scholar
  16. 16.
    Li, F.-F., Ma, J.-F., Yang, J., et al., J. Mol. Strct., 2006, vol. 787, p. 106.Google Scholar
  17. 17.
    Prida, E., BonoLmetti, E., Rabezzana, R., et al., Inorg. Chem. Commun., 2016, vol. 70, p. 35. Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • Yu. V. Kokunov
    • 1
  • V. V. Kovalev
    • 1
    Email author
  • Yu. E. Gorbunova
    • 1
  • A. V. Churakov
    • 1
  • S. A. Kozyukhin
    • 1
  1. 1.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia

Personalised recommendations