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Russian Journal of Coordination Chemistry

, Volume 45, Issue 7, pp 505–511 | Cite as

Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties

  • T. E. KokinaEmail author
  • O. V. Salomatina
  • I. I. Popadyuk
  • L. A. Glinskaya
  • I. V. Korol’kov
  • L. A. Sheludyakova
  • M. I. Rakhmanova
  • N. F. Salakhutdinov
Article

Abstract

Complexes [Zn(L)Cl2] (I), Cu(L)Cl2 ∙ H2O (II), Zn(L1)Cl2 ∙ 0.5H2O (III), and Cu(L1)Cl2 ∙ 0.5H2O (IV) (where L and L1 are the diaminopropylene and diaminoethylene derivatives of deoxycholic acid, respectively) are synthesized. The structure of mononuclear complex I is determined by X-ray structure analysis (CIF file CCDC no. 1875305). The coordination polyhedron of the Zn atom (Cl2N2) is a distorted tetrahedron. According to the X-ray diffraction data, the crystals of compounds III and IV are isostructural. It is shown by IR spectroscopy that the structures of complexes II–IV are similar to that of complex I. In the solid phase, compounds L and L1 possess photoluminescence in the visible spectral range (λmax = 440 and 415 nm, respectively). Complex formation with Zn2+ ions does not change the photoluminescence properties of L and L1.

Keywords:

deoxycholic acid complexes zinc copper synthesis crystal structure 

Notes

FUNDING

This work was supported by the state task of the Nikolaev Institute of Inorganic Chemistry (Siberian Branch, Russian Academy of Sciences) in the area of basic research.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • T. E. Kokina
    • 1
    • 2
    Email author
  • O. V. Salomatina
    • 3
  • I. I. Popadyuk
    • 3
  • L. A. Glinskaya
    • 1
  • I. V. Korol’kov
    • 1
    • 2
  • L. A. Sheludyakova
    • 1
    • 2
  • M. I. Rakhmanova
    • 1
  • N. F. Salakhutdinov
    • 2
    • 3
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk National Research State UniversityNovosibirskRussia
  3. 3.Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of SciencesNovosibirskRussia

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