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Russian Journal of Coordination Chemistry

, Volume 45, Issue 7, pp 496–504 | Cite as

Complex Formation Products in the GeO2–Tartaric Acid–CuCl2–1,10-Phenanthroline System: Syntheses and Structures

  • I. I. Seifullina
  • E. E. MartsinkoEmail author
  • E. A. Chebanenko
  • E. V. Afanasenko
  • S. V. Shishkina
  • V. V. D’yakonenko
Article

Abstract

The cation-anionic coordination compounds based on the copper(II) complexes with Phen and tartratogermanate anions, [Cu(Phen)3]2[Ge2(OH)(HTart)(µ-Tart)2] · 11H2O (I) and [CuCl(Phen)2]4[{Ge2(OH)2(µ-Tart)2}Cl2] · 4Н2О (II), with different compositions and structures (CIF files CCDC nos. 1878102 (І) and 1878103 (ІІ)) are isolated for the first time from the GeO2–tartaric acid (H4Tart)–CuCl2–1,10-phenanthroline (Phen) system. The structures of compounds I and II contain the same bridging tartrate anions. A specific feature of compound I is the additional HTart3– anion, which does not perform the bridging function but is coordinated via the bis(chelate) mode, and the hydroxyl and carboxyl groups remain vacant. The dissociation of the carboxyl group results in the formation of the tartratogermanate anion with the charge –4.

Keywords:

germanium dioxide tartaric acid 1,10-phenanthroline copper(II) coordination compounds molecular structure X-ray diffraction analysis 

Notes

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • I. I. Seifullina
    • 1
  • E. E. Martsinko
    • 1
    Email author
  • E. A. Chebanenko
    • 1
  • E. V. Afanasenko
    • 1
  • S. V. Shishkina
    • 2
    • 3
  • V. V. D’yakonenko
    • 2
  1. 1.Odessa I.I. Mechnikov National UniversityOdessaUkraine
  2. 2.Institute of Single Crystals, National Academy of Sciences of UkraineKharkovUkraine
  3. 3.Karazin National UniversityKharkovUkraine

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