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Russian Journal of Coordination Chemistry

, Volume 45, Issue 1, pp 47–55 | Cite as

Nitrilotris(methylenephosphonic) Complexes of Lanthanides [Na(H2O)x]2[LnIIINa6H(H2O)10{N(CH2PO3)3}2] · nH2O (LnIII = Pr, Nd)

  • N. V. SomovEmail author
  • F. F. Chausov
  • N. V. Lomova
  • R. M. Zakirova
  • I. V. Fedotova
  • V. G. Petrov
  • M. A. Shumilova
  • D. K. Zhirov
Article
  • 5 Downloads

Abstract

The sodium salts of lanthanide nitrilotris(mehylenephosphonate) complexes [Na(H2O)x]2[LnIIINa6H(H2O)10{N(CH2PO3)3}2] · nH2O, where LnIII = Pr (I), and Nd (II), were prepared, isolated, and studied. The isostructural crystals are monoclinic, space group P21/c, Z = 2; for complex I, a = 11.8168(7), b =  10.5403(9), c = 19.8094(10) Å, β = 94.232(5)°; for complex II, a = 11.7999(2), b = 10.5495(2), c = 19.7976(3) Å, β = 94.158(2)°. The lanthanide ions are coordinated at the center of a cage consisting of two {N(CH2PO3)3} acid residues and six sodium ions, which form P–O–Na–O–P bridges. The Ln coordination polyhedron is a regular rhombohedron (CIF files CCDC nos. 1825702 (I), 1825700 (II)).

Keywords:

neodymium praseodymium coordination compounds X-ray diffraction IR spectroscopy Raman spectroscopy thermogravimetry 

Notes

ACKNOWLEDGMENTS

This work was performed as a basic part of the State Order to Higher Educational Institutions and Scientific Organizations for Research (project no. 3.6502.2017/BCh).

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • N. V. Somov
    • 1
    Email author
  • F. F. Chausov
    • 2
    • 3
  • N. V. Lomova
    • 2
  • R. M. Zakirova
    • 3
  • I. V. Fedotova
    • 3
  • V. G. Petrov
    • 2
  • M. A. Shumilova
    • 2
  • D. K. Zhirov
    • 2
  1. 1.Lobachevsky National Research UniversityNizhny NovgorodRussia
  2. 2.Udmurt Federal Research Center, Ural Branch, Russian Academy of SciencesIzhevskRussia
  3. 3.Udmurt State UniversityIzhevskRussia

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