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Russian Journal of Coordination Chemistry

, Volume 45, Issue 1, pp 56–61 | Cite as

Methyl Propiolate Cluster Complex (Ph4P)2[W6I8(C≡C–C(O)OCH3)6]

  • M. A. MikhailovEmail author
  • P. A. Abramov
  • A. D. Mironova
  • M. R. Gallyamov
  • D. G. Sheven’
  • V. V. Pervukhin
  • M. N. Sokolov
Article
  • 2 Downloads

Abstract

A new organometallic iodide cluster complex (Bu4N)2[W6I8(C≡C–C(O)OCH3)6] (I), analogous to the previously described (Bu4N)2[Mo6I8(C≡C–C(O)OCH3)6], was obtained by the reaction of (Bu4N)2[W6I14] with silver methyl propiolate AgC≡C–C(O)OCH3. The crystal structure was established for the tetraphenylphosphonium salt (Ph4P)2[W6I8(C≡C–C(O)OCH3)6] (II). According to X-ray diffraction (CIF file CCDC no. 1829205), tungsten atoms in II are coordinated by terminal carbon atoms of methyl propiolate ligands at W–C distances of 2.220(12)–2.268(14) Å. The methyl propiolate complexes were characterized by electrospray mass spectrometry, 1H and 13C NMR spectroscopy, elemental analysis, and IR spectroscopy.

Keywords

: clusters tungsten iodides methyl propiolates organometallic compounds crystal structure 

Notes

ACKNOWLEDGMENTS

This work was supported by the Federal Agency of Scientific Organizations of Russia (Program FNI, clause V.44.4.5).

REFERENCES

  1. 1.
    Sokolov, M.N., Mihailov, M.A., Peresypkina, E.V., et al., Dalton Trans., 2011, vol. 40, p. 6375.CrossRefGoogle Scholar
  2. 2.
    Elistratova, J., Mikhailov, M., Burilov, V., et al., RSC Adv., 2014, vol. 4, p. 27922.CrossRefGoogle Scholar
  3. 3.
    Kirakci, K., Kubat, P., Dusek, M., et al., Eur. J. Inorg. Chem., 2012, p. 3107.Google Scholar
  4. 4.
    Efremova, O.A., Shestopalov, M.A., Chirtsova, N.A., et al., Dalton Trans., 2014, vol. 43, p. 6021.CrossRefGoogle Scholar
  5. 5.
    Kirakci, K., Šícha, V., Holub, J., et al., Inorg. Chem., 2014, vol. 53, p. 13012.CrossRefGoogle Scholar
  6. 6.
    Kirakci, K., Fejfarová, K., Kučeráková, M., and Lang, K., Eur. J. Inorg. Chem., 2014, p. 2331.Google Scholar
  7. 7.
    Cordier, S., Grasset, F., Molard, Y., et al., J. Inorg. Organomet. Polym. Mater., 2015, vol. 25, p. 189.CrossRefGoogle Scholar
  8. 8.
    Elistratova, J., Burilov, V., Mustafina, A., et al., Polymer, 2015, vol. 72, p. 98.CrossRefGoogle Scholar
  9. 9.
    Prevot, M., Amela-Cortes, M., Manna, S.K., et al., J. Mater. Chem., 2015, vol. 3, p. 5152.Google Scholar
  10. 10.
    Amela-Cortes, M., Paofai, S., Cordier, S., et al., Chem. Commun., 2015, vol. 51, p. 8177.CrossRefGoogle Scholar
  11. 11.
    Prevot, M., Amela-Cortes, M., Manna, S.K., et al., Adv. Funct. Mater., 2015, vol. 25, p. 4966.CrossRefGoogle Scholar
  12. 12.
    Robin, M., Kuai, W., Amela-Cortes, M., et al., ACS Appl. Mater. Interfaces, 2015, vol. 7, p. 21975.CrossRefGoogle Scholar
  13. 13.
    Solovieva, A.O., Vorotnikov, Y.A., Trifonova, K.E., et al., J. Mater. Chem., 2016, vol. 4, p. 4839.Google Scholar
  14. 14.
    Kirakci, K., Kubát, P., Fejfarová, K., et al., Inorg. Chem., 2016, vol. 55, p. 803.CrossRefGoogle Scholar
  15. 15.
    Vorotnikov, Y.A., Efremova, O.A., Vorotnikova, N.A., et al., RSC Adv., 2016, vol. 6, p. 43367.CrossRefGoogle Scholar
  16. 16.
    Sokolov, M.N., Mikhailov, M.A., Brylev, K.A., et al., Inorg. Chem., 2013, vol. 52, p. 12477.CrossRefGoogle Scholar
  17. 17.
    Sokolov, M.N., Mikhailov, M.A., Virovets, A.V., et al., Russ. Chem. Bull., 2013, vol. 62, p. 1764.CrossRefGoogle Scholar
  18. 18.
    Mikhailov, M.A., Brylev, K.A., Abramov, P.A., et al., Inorg. Chem., 2016, vol. 55, p. 8437.CrossRefGoogle Scholar
  19. 19.
    Mikhailov, M.A., Brylev, K.A., Virovets, A.V., et al., New J. Chem., 2016, vol. 40, p. 1162.CrossRefGoogle Scholar
  20. 20.
    Beltran, A., Mikhailov, M., Sokolov, M.N., et al., J. Mater. Chem. B, 2016, vol. 4, p. 5975.CrossRefGoogle Scholar
  21. 21.
    Felipe-Leon, C., Arnau del Valle, C., Perez-Lagu-na, V., et al., J. Mater. Chem. B, 2017, vol. 5, p. 6058.CrossRefGoogle Scholar
  22. 22.
    Mikhaylov, M.A., Abramov, P.A., Komarov, V.Yu., and Sokolov, M.N., Polyhedron, 2017, vol. 122, p. 241.CrossRefGoogle Scholar
  23. 23.
    Zietlow, T.C., Schaefer, W.P., Sadeghi, B., et al., Inorg. Chem., 1986, vol. 25, p. 2195.CrossRefGoogle Scholar
  24. 24.
    Mussell, R.D. and Nocera, D.G., Inorg. Chem., 1990, vol. 29, p. 3711.CrossRefGoogle Scholar
  25. 25.
    Franolic, J.D., Long, J.R., and Holm, R.H., J. Am. Chem. Soc., 1995, vol. 117, p. 8139.CrossRefGoogle Scholar
  26. 26.
    Strobele, M. and Meyer, H.-J., Inorg. Chem., 2017, vol. 56, p. 5880.CrossRefGoogle Scholar
  27. 27.
    Strobele, M., Enseling, D., Jüstel, T., and Meyer, H.-J., Z. Anorg. Allg. Chem., 2016, vol. 642, p. 1435.CrossRefGoogle Scholar
  28. 28.
    Hogue, R.D. and Mccarley, R.E., Inorg. Chem., 1970, vol. 9, p. 1354.CrossRefGoogle Scholar
  29. 29.
    Mikhailov, M.A., Gushchin, A.L., Gallyamov, M.R., et al., Russ. J. Coord. Chem., 2017, vol. 43, p. 172.CrossRefGoogle Scholar
  30. 30.
    Riehl, L., Seyboldt, A., Ströbele, M., et al., Dalton Trans., 2016, vol. 45, p. 15500.CrossRefGoogle Scholar
  31. 31.
    Sokolov, M.N., Brylev, K.A., Abramov, P.A., et al., Eur. J. Inorg. Chem., 2017, p. 4131.Google Scholar
  32. 32.
    Sheldrick, G.M., SADABS, Göttingen: Univ. of Göttingen, 1996.Google Scholar
  33. 33.
    Hübschle, C.B., Sheldrick, G.M., and Dittrich, B., J. Appl. Crystallogr., 2011, vol. 44, p. 1281.CrossRefGoogle Scholar
  34. 34.
    Saito, T., Nishida, M., Yamagata, T., et al., Inorg. Chem., 1986, vol. 25, p. 1111.CrossRefGoogle Scholar
  35. 35.
    Yamagata, T., Okiyama, H., Imoto, H., and Saito, T., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1997, vol. 53, p. 859.CrossRefGoogle Scholar
  36. 36.
    Saito, T., Manabe, H., Yamagata, T., and Imoto, H., Inorg. Chem., 1987, vol. 26, p. 1362.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • M. A. Mikhailov
    • 1
    Email author
  • P. A. Abramov
    • 1
    • 2
  • A. D. Mironova
    • 1
  • M. R. Gallyamov
    • 1
  • D. G. Sheven’
    • 1
  • V. V. Pervukhin
    • 1
  • M. N. Sokolov
    • 1
    • 2
    • 3
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia
  3. 3.Kazan Federal UniversityKazanRussia

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