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Russian Journal of Coordination Chemistry

, Volume 44, Issue 12, pp 765–771 | Cite as

Syntheses and Structures of the Hexacoordinated Antimony Complexes: Ph3(C2H4O2)Sb⋅⋅⋅DMSO, (3-FC6H4)3(C2H4O2)Sb⋅⋅⋅DMSO, and (4-MeC6H4)3(C6H4O2)Sb⋅⋅⋅DMSO

  • V. V. SharutinEmail author
  • O. K. Sharutina
  • N. A. Shalabanova
Article
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Abstract

Complexes Ph3(C2H4O2)Sb⋅⋅⋅DMSO (I), (3-FC6H4)3(C2H4O2)Sb⋅⋅⋅DMSO (II), and (4‑MeC6H4)3-(C6H4O2)Sb⋅⋅⋅DMSO (III) are synthesized by the reactions of triarylantimony with ethylene glycol or pyrocatechol in the presence of an oxidant and dimethyl sulfoxide (DMSO). According to the X-ray diffraction analysis data, the Sb atoms in the complexes have the coordination of a distorted octahedron with the chelate cycle (C2H4O2 or C6H4O2) and two aryl groups in the equatorial plane, and the third aryl group and DMSO molecule occupy the axial positions. The СSbO axial angles are 173.59(5)° (I); 175.96(8)°, 175.93(8)° (II); and 174.07(8)° (III). The Sb⋅⋅⋅О=SMe2 distances (2.346(2)−2.407(2) Å) considerably exceed the sum of covalent radii of the atoms.

Keywords:

triphenylantimony tris(3-fluorophenyl)antimony ethylene glycol pyrocatechol dimethyl sulfoxide oxidation synthesis hexacoordinated antimony(V) complexes X-ray diffraction analysis 

Notes

ACKNOWLEDGMENTS

This work was supported by the Ministry of Education and Science of the Russian Federation, project no. 4.6151.2017/8.9.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • V. V. Sharutin
    • 1
    Email author
  • O. K. Sharutina
    • 1
  • N. A. Shalabanova
    • 1
  1. 1.National Research Southern Ural State UniversityChelyabinskRussia

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