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Russian Journal of Coordination Chemistry

, Volume 44, Issue 12, pp 772–778 | Cite as

Tetra- and Pentanuclear Iodobismuthates with the Cation Based on 2,3,5,6-Tetramethylpyrazine: Syntheses and Crystal Structures

  • A. N. Usoltsev
  • S. A. AdoninEmail author
  • P. A. Abramov
  • M. N. Sokolov
  • V. P. Fedin
Article
  • 18 Downloads

Abstract

Complexes (HTMP)4[Bi4I16] · 2H2O · 2(CH3)2CO (I) and (HTMP)3[Bi5I18] · 5THF (II) have been synthesized by the reactions of BiI3 and 2,3,5,6-tetramethylpyrazine (TMP) in acetone and tetrahydrofuran (THF), respectively. The crystal structures of both compounds were determined by X-ray diffraction analysis (СIF files CCDC nos. 1817306 (I) and 1817307 (II)). In both cases, the complexes in the solid state feature supramolecular contacts between the π systems of the cations and iodide ligands of the anions.

Keywords:

bismuth halide complexes tetramethylpyrazine X-ray diffraction analysis supramolecular contacts 

Notes

ACKNOWLEDGMENTS

This work was supported by the Russian Science Foundation, project no. 14-23-00013. S.A. Adonin is grateful to the Council for Grants of the President of the Russian Federation.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. N. Usoltsev
    • 1
  • S. A. Adonin
    • 1
    • 2
    Email author
  • P. A. Abramov
    • 1
    • 2
  • M. N. Sokolov
    • 1
    • 3
  • V. P. Fedin
    • 1
    • 2
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia
  3. 3.Kazan (Volga region) Federal UniversityKazanRussia

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