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Russian Journal of Coordination Chemistry

, Volume 44, Issue 12, pp 818–823 | Cite as

A New Heterometallic Pb(II)–Ca(II) Coordination Polymer with 2D Pb–O–Ca Inorganic Connectivity

  • Z. An
  • J. Gao
  • J. WangEmail author
Article
  • 10 Downloads

Abstract

A new heterometallic-organic framework, namely [PbCa(Mbdc)2(DMF)]n (I) (H2Mbdc = isophthalic acid, DMF = N,N'-dimethylformamide), was synthesized by the solvothermal reactions of Pb(NO3)2, Ca(NO3)2 · 4H2O and H2Mbdc. Single crystal X-ray diffraction analysis (CIF file CCDC no. 1567197) revealed that compound I features a 3D pillar-layered framework with 2D inorganic Pb–O–Ca connectivity. Thermal analysis indicated that the framework of compound I can be stable up to 320°C, and luminescent property investigation indicated that compound I exhibits intense luminescence at room temperature.

Keywords:

solvothermal reactions heterometallic compound inorganic connectivity luminescence 

Notes

ACKNOWLEDGMENTS

This work was supported by the Guangdong University of Petrochemical Technology.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.School of Chemical Engineering, Guangdong University of Petrochemical Technology MaomingP.R. China
  2. 2.Department of Pharmacy, Mudanjiang Medical UniversityMudanjiangP.R. China
  3. 3.School of Environmental and Biological Engineering, Guangdong University of Petrochemical TechnologyMaomingP.R. China

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