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Russian Journal of Coordination Chemistry

, Volume 44, Issue 11, pp 678–687 | Cite as

Syntheses and Characterization of Coordination Compounds of 3d-Metal 5-Sulfosalicylates with Phenylacethydrazide: Crystal Structure of [Ni(L)3]HSSal · 3H2O (L is Phenylacethydrazide, and HSSal2– is 5-Sulfosalicylic Acid Anion)

  • T. V. Koksharova
  • V. S. Sergienko
  • M. D. Surazhskaya
  • T. V. Mandzii
  • E. N. Fadeev
Article
  • 10 Downloads

Abstract

The complexes of 3d-metal 5-sulfosalicylates with phenylacethydrazide are synthesized: [Co(L)3]HSSal · 3H2O (I), [Ni(L)3]HSSal · 3H2O (II), and [Zn(L)3]HSSal · 6H2O (III) (L is phenylacethydrazide, and HSSal2– is 5-sulfosalicylic acid anion). Compounds I–III are characterized by the methods of chemical analysis, IR spectroscopy, diffuse reflectance spectroscopy, luminescence, and thermogravimetry. Compound II is studied by X-ray diffraction analysis (СIF file CCDC no. 1819696). In the complex cation [Ni(L)3]2+, the nickel atom has a face octahedral coordination mode by three O atoms and three N atoms of three bidentate chelate ligands L. The complex cations, HSSal2– anions, and crystallization water molecules are joined by a branched system of hydrogen bonds. Complexes I–III are luminescent, and complex III exhibits the brightest luminescence.

Keywords:

synthesis IR spectroscopy diffuse reflectance spectroscopy luminescence thermogravimetry X-ray diffraction analysis 5-sulfosalicylates of 3d metals 

Notes

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • T. V. Koksharova
    • 1
  • V. S. Sergienko
    • 2
    • 3
  • M. D. Surazhskaya
    • 2
  • T. V. Mandzii
    • 1
  • E. N. Fadeev
    • 4
  1. 1.Odessa National UniversityOdessaUkraine
  2. 2.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia
  3. 3.All-Russia Institute of Scientific and Technical Information, Russian Academy of SciencesMoscowRussia
  4. 4.Bogatskii Physicochemical Institute, National Academy of Sciences of UkraineOdessaUkraine

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