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Russian Journal of Coordination Chemistry

, Volume 44, Issue 10, pp 613–618 | Cite as

Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4

  • A. N. Makhinya
  • M. A. Il’in
  • I. V. Korol’kov
  • I. A. Baidina
Article
  • 5 Downloads

Abstract

The slow evaporation of an acetone solution containing trans-[Ru(NO)Py4(OH)]2+ cations and hexafluorophosphate anions results in the crystallization of trans-[Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO (I). The reactions of trans‑[Ru(NO)Py4(OH)]Cl2 ⋅ H2O with solutions of chloric or hydrochloric acid followed by the evaporation of the reaction solutions at ambient temperature afford trans-[Ru(NO)Py4(H2O)](ClO4)3 (II) or [H5O2]2[Ru(NO)Py4Cl]Cl4 (III), respectively. The obtained chloride complex III is unstable and at ambient temperature eliminates hydrogen chloride to transform into trans-[Ru(NO)Py4Cl]Cl2 ⋅ 4H2O (IV). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files ССDC nos. 1421042 (I) and 1421041 (III)).

Keywords:

nitrosoruthenium complexes amino complexes pyridine chloride complexes hydroxo complexes X-ray structure analysis IR spectroscopy 

Notes

ACKNOWLEDGMENTS

The authors are grateful to N.I. Alferova for recording IR spectra and to N.P. Korotkevich for the detection of powder diffraction patterns.

This work was supported by the Complex program for basic research of the Siberian Branch of the Russian Academy of Sciences, project no. II.1.16.1.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. N. Makhinya
    • 1
    • 2
  • M. A. Il’in
    • 1
    • 2
  • I. V. Korol’kov
    • 1
    • 2
  • I. A. Baidina
    • 1
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia

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