Physics of the Solid State

, Volume 61, Issue 11, pp 2117–2129 | Cite as

Spectral and Structural Characteristics of (Lu1 – xEux)2(WO4)3 Tungstates

  • S. Z. ShmurakEmail author
  • V. V. Kedrov
  • A. P. Kiselev
  • T. N. Fursova
  • I. I. Zver’kova
  • S. S. Khasanov


The structure, luminescence, and IR absorption spectra of (Lu1 – xEux)2(WO4)3 solid solutions are studied in a wide range of europium concentrations (0 ≤ x ≤ 1). As the europium concentration increases, two types of crystalline phases sequentially alternate. An orthorhombic phase (space group Pbcn) of tungstate solid solutions is observed at 0 ≤ x < 0.5. In the range 0.5 ≤ x ≤ 0.8, along with the orthorhombic phase, a monoclinic phase (space group C2/c) appears; at x > 0.8, the solid solution has a monoclinic structure. The correspondence between the structure and spectral characteristics of these compounds is found. A change in the structure state leads to not only changes in luminescence spectra, but also in tungstate luminescence excitation spectra. In connection with the hydrophilicity of (Lu1 – xEux)2(WO4)3 solid solutions, the water adsorption isotherm for tungstate samples and its effect on their spectral and structural characteristics is studied. It is found that the luminescence maximum under resonant excitation of Eu3+ ions is observed in samples with monoclinic structure C2/c at x ~ 0.9.


phosphors for light-emitting diodes tungstates of rare-earth elements X-ray diffraction analysis IR spectroscopy luminescence spectra 



The authors are grateful to the Shared Service Center of the Institute of Solid State Physics of the Russian Academy of Sciences for IR spectroscopy studies of samples and their morphology. The authors are grateful to N.F. Prokopyuk for assistance in experiments.


This study was performed within the State contract of the Solid State Physics Institute, Russian Academy of Sciences.


The authors declare that they have no conflicts of interest.


  1. 1.
    Y. H. Zhou, J. Lin, S. B. Wang, and H. J. Zhang, Opt. Mater. 20, 13 (2002).ADSCrossRefGoogle Scholar
  2. 2.
    V. Dmitriev, V. Sinisyn, R. Dilanyan, D. Machon, A. Kuznetsov, E. Ponyatovsky, G. Lucazeau, and H.‑P. Weber, J. Phys. Chem. Solids 64, 307 (2003).ADSCrossRefGoogle Scholar
  3. 3.
    A. P. Kiselev, S. Z. Shmurak, B. S. Red’kin, V. V. Sinitsyn, I. M. Shmyt’ko, E. A. Kudrenko, and E. G. Ponyatovskii, Phys. Solid State 48, 1544 (2006).ADSCrossRefGoogle Scholar
  4. 4.
    S. Z. Shmurak, A. P. Kiselev, N. V. Klassen, V. V. Sinitsyn, I. M. Shmyt’ko, B. S. Red’kin, and S. S. Khasanov, IEEE Trans. Nucl. Sci. 55, 1128 (2008).ADSCrossRefGoogle Scholar
  5. 5.
    S. Z. Shmurak, A. P. Kiselev, D. M. Kurmasheva, B. S. Red’kin, and V. V. Sinitsyn, J. Exp. Theor. Phys. 110, 759 (2010).ADSCrossRefGoogle Scholar
  6. 6.
    S. Z. Shmurak, V. V. Kedrov, A. P. Kiselev, and I. M. Shmyt’ko, Phys. Solid State 57, 18 (2015).ADSCrossRefGoogle Scholar
  7. 7.
    J. Yang, C. Li, X. Zhang, Z. Quan, C. Zhang, H. Li, and J. Lin, Chem. Eur. J. 14, 4336 (2008).CrossRefGoogle Scholar
  8. 8.
    J. Hälsö, Inorg. Chim. Acta 139, 257 (1987).CrossRefGoogle Scholar
  9. 9.
    S. Z. Shmurak, V. V. Kedrov, A. P. Kiselev, and I. M. Shmyt’ko, Phys. Solid State 57, 18 (2015).ADSCrossRefGoogle Scholar
  10. 10.
    S. Z. Shmurak, V. V. Kedrov, A. P. Kiselev, T. N. Fursova, and I. M. Shmyt’ko, Phys. Solid State 57, 1588 (2015).ADSCrossRefGoogle Scholar
  11. 11.
    S. Z. Shmurak, V. V. Kedrov, A. P. Kiselev, T. N. Fursova, I. I. Zver’kova, and S. S. Khasanov, Phys. Solid State 61, 632 (2019).ADSCrossRefGoogle Scholar
  12. 12.
    H. Y. Chen, Mater. Res. Bull. 14, 1583 (1979).CrossRefGoogle Scholar
  13. 13.
    V. A. Efremov, B. I. Lazoryak, and V. K. Trunov, Sov. Phys. Crystallogr. 26, 38 (1981).Google Scholar
  14. 14.
    E. M. Levin, R. S. Roth, and J. B. Martin, Am. Mineral. 46, 1030 (1961).Google Scholar
  15. 15.
    L. N. Brixner, J. R. Barkley, and W. Jeitschko, in Handbook on the Physics and Chemistry of Rare Earth, Ed. by K. A. Gschneidner, Jr. and L. Eyring (North-Holland, Amsterdam, 1979), p. 609.Google Scholar
  16. 16.
    K. Nassau, H. J. Levinstein, and G. M. Loiacono, J. Phys. Chem. Solids 26, 1805 (1965).ADSCrossRefGoogle Scholar
  17. 17.
    N. S. Akhmetov, Inorganic Chemistry (Vyssh. Shkola, Moscow, 1975), p. 548 [in Russian].Google Scholar
  18. 18.
    Z. Y. Li, W. B. Song, and E. J. Liang, J. Phys. Chem. C 115, 17806 (2011).CrossRefGoogle Scholar
  19. 19.
    K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Mir, Moscow, 1968; Wiley, New York, 1986).Google Scholar
  20. 20.
    J. Hanuza, M. Maczka, K. Hermanowicz, M. Andruszkiewicz, A. Pietraszko, W. Strek, and P. Deren, J. Solid State Chem. 105, 49 (1993).ADSCrossRefGoogle Scholar
  21. 21.
    L. J. Burcham and I. E. Wachs, Spectrochim. Acta A 54, 1355 (1998).ADSCrossRefGoogle Scholar
  22. 22.
    M. Maczka, K. Hermanowicza, and J. Hanuza, J. Mol. Struct. 744–747, 283 (2005).ADSCrossRefGoogle Scholar
  23. 23.
    G. Blasse and M. Ouwerkerk, J. Electrochem. Soc.: Solid-State Sci. Technol. 27, 429 (1980).Google Scholar
  24. 24.
    M. Rahimi-Nasrabadi, S. M. Pourmortazavi, M. R. Gan-jali, A. R. Banan, and F. Ahmadi, J. Mol. Struct. 1074, 85 (2014).ADSCrossRefGoogle Scholar
  25. 25.
    A. W. Sleight and L. H. Brixner, J. Solid State Chem. 7, 172 (1973).ADSCrossRefGoogle Scholar
  26. 26.
    S. Neeraj, N. Kijima, and A. Cheetham, Chem. Phys. Lett. 387, 2 (2004).ADSCrossRefGoogle Scholar
  27. 27.
    A. Xie, X. Yuan, F. Wang, Y. Shi, J. Li, L. Liu, and Z. Mu, J. Alloys Compd. 501, 124 (2010).CrossRefGoogle Scholar
  28. 28.
    Z. Zhang, H. Zhang, C. Duan, J. Yuan, X. Wang, D. Xiong, H. Chen, and J. Zhao, J. Alloys Compd. 466, 258 (2008).CrossRefGoogle Scholar
  29. 29.
    G. Blasse, G. J. Dirksen, and L. H. Brixner, J. Solid State Chem. 46, 294 (1983).ADSCrossRefGoogle Scholar
  30. 30.
    M. A. El’yashevich, Spectroscopy of Rare Earths (GITTL, Moscow, 1953), p. 456 [in Russian].Google Scholar
  31. 31.
    M. I. Gaiduk, V. F. Zolin, and L. S. Gaigerova, Europium Luminescence Spectra (Nauka, Moscow, 1974), p. 195 [in Russian].Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • S. Z. Shmurak
    • 1
    Email author
  • V. V. Kedrov
    • 1
  • A. P. Kiselev
    • 1
  • T. N. Fursova
    • 1
  • I. I. Zver’kova
    • 1
  • S. S. Khasanov
    • 1
  1. 1.Solid State Physics Institute, Russian Academy of SciencesChernogolovkaRussia

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