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Physics of the Solid State

, Volume 60, Issue 12, pp 2579–2592 | Cite as

Energy Transfer from Ce3+ to Tb3+ in Yttrium and Gadolinium Orthoborates Obtained by Hydrothermal Synthesis

  • S. Z. ShmurakEmail author
  • V. V. Kedrov
  • A. P. Kiselev
  • T. N. Fursova
  • O. G. Rybchenko
OPTICAL PROPERTIES

Abstract

We studied the structure, IR absorption spectra, the spectral characteristics of photoluminescence and morphology of cerium- and terbium-doped orthoborates of gadolinium and yttrium obtained by hydrothermal synthesis at 200°C, as well as solid solutions of orthoborates on the basis of yttrium, gadolinium, and lutetium with composition RECe0.01Tb0.1BO3 (RE = Lu0.5Gd0.39, Lu0.5Y0.39, and Y0.5Gd0.39). The X-ray diffraction spectrum of yttrium orthoborate Y1 – x  yCexTbyBO3 is described by a hexagonal lattice with space group P63/m, which, after annealing at 970°C, transforms into a monoclinic lattice with space group C2/c. High-temperature annealing of the studied orthoborates leads to a multiple, more than two orders of magnitude, increase in the luminescence intensity of Tb3+ ions when the samples are excited in the absorption band of cerium ions. This effect is the result of a significant increase in the concentration of Ce3+ ions in the orthoborates at high temperatures. It is shown that the luminescence of terbium ions is due to energy transfer from Ce3+ to Tb3+, which proceeds with high efficiency (∼85%) by the mechanism of dipole-dipole interaction between cerium and terbium.

Notes

ACKNOWLEDGMENTS

We thank E.Yu. Postnova for the study of the morphology of samples and N.F. Prokopyuk for assistance in conducting the experiments.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • S. Z. Shmurak
    • 1
    Email author
  • V. V. Kedrov
    • 1
  • A. P. Kiselev
    • 1
  • T. N. Fursova
    • 1
  • O. G. Rybchenko
    • 1
  1. 1.Institute of Solid State Physics, Russian Academy of SciencesChernogolovkaRussia

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