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Journal of Analytical Chemistry

, Volume 74, Issue 11, pp 1089–1095 | Cite as

Simultaneous Determination of Anthraquinone and Bisphenol A in Pulp and Paper Products by High Performance Liquid Chromatography‒Tandem Mass Spectrometry

  • A. S. Amosov
  • N. V. Ul’yanovskii
  • D. S. KosyakovEmail author
ARTICLES
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Abstract

A procedure for the rapid simultaneous determination of anthraquinone and bisphenol A in paper and cardboard is proposed based on a combination of extraction with subcritical methanol and subsequent analysis of the extracts by HPLC‒tandem mass spectrometry. The achieved limits of detection are 25 and 250 µg/kg for anthraquinone and bisphenol A, respectively, and fully meet present-day safety requirements for pulp and paper products. The total duration of the analysis, including sample preparation, is not more than 45 min. The sensitivity of anthraquinone determination is 1‒2 orders of magnitude higher than that of the known procedures, including those with the preconcentration of analytes. The results obtained were successfully used to study paper and cardboard samples, in most of which unacceptably high levels of the anthraquinone concentration were found.

Keywords:

HPLC tandem mass spectrometry anthraquinone bisphenol A pressurized liquid extraction paper cardboard 

Notes

FUNDING

The work was done using the equipment of the Core Facility Center “Arktika” of the Lomonosov Northern (Arctic) Federal University with the financial support from the Ministry of Education and Science of the Russian Federation, project no. 4.2518.2017/4.6.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. S. Amosov
    • 1
  • N. V. Ul’yanovskii
    • 1
  • D. S. Kosyakov
    • 1
    Email author
  1. 1.Lomonosov Northern (Arctic) Federal University, Core Facility Center “Arktika”ArkhangelskRussia

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