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Journal of Analytical Chemistry

, Volume 74, Issue 8, pp 729–737 | Cite as

Covalent Coatings of Quartz Capillaries for the Electrophoretic Determination of Biologically Active Analytes

  • L. A. Kartsova
  • A. V. KravchenkoEmail author
  • E. A. Kolobova
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Abstract

One of the main limitations of capillary electrophoresis (CE) is the sorption of basic compounds on the walls of a quartz capillary. To prevent this phenomenon in CE, supporting electrolytes with various additives that prevent the sorption of analytes due to the formation of dynamic coatings are commonly used. Alternatively, covalent coatings, which have a number of advantages and expand the analytical capabilities of CE, are used. The main methods of the formation of coatings covalently bound to the walls of a quartz capillary are considered.

Keywords:

capillary electrophoresis capillary electrochromatography covalent coatings modifiers polymers ionic liquids nanoparticles metal-organic frameworks 

Notes

FUNDING

This work was supported by the Russian Foundation for Basic Research (grant no. 17-03-01282-a).

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • L. A. Kartsova
    • 1
  • A. V. Kravchenko
    • 1
    Email author
  • E. A. Kolobova
    • 1
    • 2
  1. 1.Institute of Chemistry, St. Petersburg State UniversitySt. PetersburgRussia
  2. 2.Nikiforov Russian Center of Emergency and Radiation Medicine, Ministry of the Russian Federation for Civil Defense, Emergencies, and Elimination of Consequences of Natural DisastersSt. PetersburgRussia

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