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Journal of Analytical Chemistry

, Volume 74, Issue 7, pp 672–678 | Cite as

Simultaneous Determination of Copper(II) and Cobalt(II) Ions, Copper(II) and Manganese(II) Ions in Drinking Water Using Indicator Test Tubes Based on Carboxylic Cation-Exchangers

  • V. V. ZharkovaEmail author
  • L. A. Bobkova
ARTICLES
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Abstract

We investigated a possibility of determining two metal ions (Cu2+ and Co2+, Cu2+ and Mn2+) in a single water sample using an indicator test tube filled with a carboxylic cation exchanger of a macrocellular (KB-2E-10, KB-2E-16) or a macroporous (Tokem-250) structure. Under dynamic conditions, the separation of the chromatographic zones of colored Cu2+ and Co2+ ions was achieved in the presence of water macro components, that is, Ca2+ and Mg2+ ions. An analytical reagent, formaldoxime, was used to determine colorless Mn2+ ions. The performance characteristics of the developed procedures are determined. The lowest limit of detection for ions was obtained using a KB-2E-16 cation exchanger; it is 0.016 mg/L for Cu2+, 0.045 mg/L for Co2+, and 0.003 mg/L for Mn2+. The proposed procedures were used to analyze real samples for the concentration of Co2+ and Cu2+ or Mn2+ and Cu2+ on their simultaneous presence. The accuracy of the results was evaluated by the standard addition method.

Keywords:

carboxylic cation exchangers test determination of Mn(II) Co(II) and Cu(II) ions indicator tubes 

Notes

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Department of Chemistry, National Research Tomsk State UniversityTomskRussia

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