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Colloid Journal

, Volume 80, Issue 5, pp 578–586 | Cite as

Adsorption-Induced Deformation of Adsorbents

  • A. A. Fomkin
  • A. V. Shkolin
  • A. L. Pulin
  • I. E. Men’shchikov
  • E. V. Khozina
Article
  • 2 Downloads

Abstract

Adsorption-induced deformation of AR-V and AUK carbon adsorbents and NaX zeolite has been studied upon adsorption of n5Н12, n6Н18, n7Н16, and CO2 at temperatures of 193−423 K. It has been shown that adsorption-induced deformation is positive upon the physical adsorption of gases and vapors on the surface of a nonporous (macroporous) solid when the excess adsorption is positive. When calculating the adsorption-induced deformation in the region of the capillary-condensation filling of mesopores, the additional pressure in capillaries, which is negative (contraction of an adsorbent), must be taken into account in the case of wetting a solid surface with a liquid adsorbate. The compressibility of AUK microporous carbon adsorbent as a porous solid is almost independent of the temperature and the properties of an adsorbate, and, for adsorption of n-C5H10 and n-C7H16 hydrocarbons and CO2, it is γа = (5.6 ± 0.6) × 10−6 bar−1. The compressibility of AUK adsorbent appears to be 87% higher than that of nonporous graphite.

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References

  1. 1.
    Rehbinder, P.A., VI s"ezd russkikh fizikov (VI Congress of Russian Physicists), Moscow: OGIZ, 1928.Google Scholar
  2. 2.
    Rehbinder, P.A., Usp. Fiz. Nauk, 1972, vol. 108, p. 3.CrossRefGoogle Scholar
  3. 3.
    Bangham, D.H. and Fakhoury, N., Nature (London), 1928, vol. 122, p. 681.CrossRefGoogle Scholar
  4. 4.
    Bangham, D.H. and Fakhoury, N., Proc. R. Soc. London A, 1930, vol. 130, p. 81.CrossRefGoogle Scholar
  5. 5.
    Bangham, D.H. and Razouk, R.J., Trans. Faraday Soc., 1937, vol. 33, p. 1463.CrossRefGoogle Scholar
  6. 6.
    Haines, R.S. and McIntosh, R., J. Chem. Phys., 1947, vol. 15, p. 28.CrossRefGoogle Scholar
  7. 7.
    Yates, D.J.C., J. Phys. Chem., 1956, vol. 60, p. 543.CrossRefGoogle Scholar
  8. 8.
    Flood, E.A., Can. J. Chem., 1957, vol. 35, p. 48.CrossRefGoogle Scholar
  9. 9.
    Kononyuk, V.F., Sarakhov, A.I., and Dubinin, M.M., Izv. Akad. Nauk SSSR, Ser. Khim., 1972, no. 5, p. 45.Google Scholar
  10. 10.
    Bering, B.P., Krasil’nikova, O.K., and Serpinskii, V.V., Dokl. Akad. Nauk SSSR, 1976, vol. 231, p. 373.Google Scholar
  11. 11.
    Warne, M.R., Allan, N.L., and Cosgrove, T., Phys. Chem. Chem. Phys., 2000, vol. 2, p. 3663.CrossRefGoogle Scholar
  12. 12.
    Jakubov, T.S. and Mainwaring, D.E., Phys. Chem. Chem. Phys., 2002, vol. 4, p. 5678.CrossRefGoogle Scholar
  13. 13.
    Fomkin, A.A. and Pulin, A.L., Izv. Akad. Nauk, Ser. Khim., 1999, p. 1887.Google Scholar
  14. 14.
    Fomkin, A.A., Regent, N.I., and Sinitsyn, V.A., Izv. Akad. Nauk, Ser. Khim., 2000, p. 1018.Google Scholar
  15. 15.
    Yakovlev, V.Yu., Fomkin, A.A., Tvardovskii, A.V., Sinitsyn, V.A., and Pulin, A.L., Izv. Akad. Nauk, Ser. Khim., 2003, p. 338.Google Scholar
  16. 16.
    Fomkin, A.A., Adsorption, 2005, vol. 11, p. 425.CrossRefGoogle Scholar
  17. 17.
    Gor, G.Y. and Neimark, A.V., Langmuir, 2010, vol. 26, p. 13021.CrossRefGoogle Scholar
  18. 18.
    Ustinov, E.A. and Do, D.D., Carbon, 2006, vol. 44, p. 2652.CrossRefGoogle Scholar
  19. 19.
    Rusanov, A.I., Colloid J., 2007, vol. 69, p. 807.CrossRefGoogle Scholar
  20. 20.
    Shkolin, A.V., Potapov, S.V., and Fomkin, A.A., Colloid J., 2015, vol. 77, p. 812.CrossRefGoogle Scholar
  21. 21.
    Kel'tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Fundamentals of Adsorption Technique), Moscow: Khimiya, 1976.Google Scholar
  22. 22.
    Zhukova, A.I., Bondarenko, S.V., Sharkina, E.V., Rudenko, V.M., and Tarasevich, Yu.I., Fiz.-Khim. Mekh. Liofil’nost’ Dispers. Sist., 1977, no. 9, p. 9.Google Scholar
  23. 23.
    Kononyuk, V.F., Sarakhov, A.I., and Dubinin, M.M., Izv. Akad. Nauk SSSR, Ser. Khim., 1972, p. 1691.Google Scholar
  24. 24.
    Tvardovskii, A.V., Tarasovich, Yu.I., Zhukova, A.I., Fomkin, A.A., and Serpinskii, V.V., Izv. Akad. Nauk, Ser. Khim., 1992, p. 1979.Google Scholar
  25. 25.
    Fomkin, A.A. and Pulin, A.L., Izv. Akad. Nauk, Ser. Khim., 1996, p. 336.Google Scholar
  26. 26.
    Bakaev, V.A., Izv. Akad. Nauk SSSR, Ser. Khim., 1971, p. 2648.Google Scholar
  27. 27.
    Fomkin, A.A., Adsorption, 2005, vol. 11, p. 425.CrossRefGoogle Scholar
  28. 28.
    Gusev, V. and Fomkin, A., J. Colloid Interface Sci., 1994, vol. 162, p. 279.CrossRefGoogle Scholar
  29. 29.
    Pulin, A.L., Fomkin, A.A., Sinitsyn, V.A., and Pribylov, A.A., Izv. Akad. Nauk, Ser. Khim., 2001, p. 57.Google Scholar
  30. 30.
    Dubinin, M.M., Adsorbtsiya i poristost' (Adsorption and Porosity), Moscow: VAKhZ, 1972.Google Scholar
  31. 31.
    Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area and Porosity, London: Academic, 1982.Google Scholar
  32. 32.
    Tolmachev, A.M., Adsorbtsiya gazov, parov i rastvorov (The Adsorption of Gases, Vapors, and Solutions), Moscow: Granitsa, 2012.Google Scholar
  33. 33.
    Fomkin, A.A., Serpinskii, V.V., and Fidler, K., Izv. Akad. Nauk SSSR, Ser. Khim., 1982, p. 1207.Google Scholar
  34. 34.
    Tolmachev, A.M., Firsov, D.A., Anuchin, K.M., and Fomkin, A.A., Colloid J., 2008, vol. 70, p. 486.CrossRefGoogle Scholar
  35. 35.
    Guggengeim, E.A., Sovremennaya termodinamika, izlozhennaya po metodu U. Gibbsa (Modern Thermodynamics Presented by the W. Gibbs Method), Leningrad-Moscow: GNTI Khim. Lit., 1941, p. 138.Google Scholar
  36. 36.
    Brunauer, S., The Adsorption of Gases and Vapors. Vol. 1. Physical Adsorption, Princeton, 1948.Google Scholar
  37. 37.
    Maggs, F.A.P., Trans. Faraday Soc., 1946, vol. 42, p. 284.CrossRefGoogle Scholar
  38. 38.
    Yates, D.J.C., Proc. Phys. Soc., 1952, vol. 65, p. 80.CrossRefGoogle Scholar
  39. 39.
    Yates, D.J.C., Proc. R. Soc. London, 1954, p. 526.Google Scholar
  40. 40.
    Yates, D.J.C., Adv. Catal., 1960, vol. 12, p. 265.Google Scholar
  41. 41.
    Nabiulin, V.V., Fomkin, A.A., and Tvardovskii, A.V., Russ. J. Phys. Chem., 2011, vol. 85, p. 1960.CrossRefGoogle Scholar
  42. 42.
    Nguen tkhi Min Khien, Cand. Sci. (Chem.) Dissertation, Moscow: Inst. of Physical Chemistry, 1986.Google Scholar
  43. 43.
    Kononyuk, V.F., Sarakhov, A.I., and Dubinin, M.M., Dokl. Akad. Nauk SSSR, 1971, vol. 198, p. 638.Google Scholar
  44. 44.
    Kononyuk, V.F., Sarakhov, A.I., and Dubinin, M.M., Izv. Akad. Nauk SSSR, Ser. Khim., 1972, p. 1691.Google Scholar
  45. 45.
    Radeke, K.H., Z. Phys. Chem., 1977, vol. 258, p. 200.Google Scholar
  46. 46.
    Dubinin, M.M., Chem. Rev., 1960, vol. 60, p. 236.CrossRefGoogle Scholar
  47. 47.
    Pulin, A.L. and Fomkin, A.A., Izv. Akad. Nauk, Ser. Khim., 2004, p. 1570.Google Scholar
  48. 48.
    Yakovlev, V.Yu., Fomkin, A.A., and Tvardovski, A.V., J. Colloid Interface Sci., 2004, vol. 280, p. 305.CrossRefGoogle Scholar
  49. 49.
    Yakovlev, V.Yu., Fomkin, A.A., and Tvardovski, A.V., J. Colloid Interface Sci., 2003, vol. 268, p. 33.CrossRefGoogle Scholar
  50. 50.
    Yakovlev, V.Yu., Fomkin, A.A., Tvardovskii, A.V., and Sinitsyn, V.A., Izv. Akad. Nauk, Ser. Khim., 2005, p. 1331.Google Scholar
  51. 51.
    Pauling, L., The Nature of The Chemical Bond, Ithaca: Cornell Univ. Press, 1960.Google Scholar
  52. 52.
    Yakovlev, V.Yu., Fomkin, A.A., Tvardovskii, A.V., Sinitsyn, V.A., and Pulin, A.L., Izv. Akad. Nauk, Ser. Khim., 2003, p. 338.Google Scholar
  53. 53.
    Pulin, A.L., Fomkin, A.A., Sinitsyn, V.A., and Pribylov, A.A., Izv. Akad. Nauk, Ser. Khim., 2001, p. 57.Google Scholar
  54. 54.
    Breck, D., Zeolite Molecular Sieves, New York: Wiley, 1974.Google Scholar
  55. 55.
    Serpinskii, V.V. and Yakubov, T.S., Izv. Akad. Nauk SSSR, Ser. Khim., 1981, p. 71.Google Scholar
  56. 56.
    Berezin, G.I. and Kozlov, A.A., Dokl. Akad. Nauk SSSR, 1980, vol. 253, p. 373.Google Scholar
  57. 57.
    Jakubov, T.S., Phys. Chem. Chem. Phys., 2002, p. 5678.Google Scholar
  58. 58.
    Rusanov, A.I. and Kuni, F.M., Russ. J. Gen. Chem., 2007, vol. 77, p. 371.CrossRefGoogle Scholar
  59. 59.
    Fomkin, A.A. and Pulin, A.L., Izv. Akad. Nauk, Ser. Khim., 1999, p. 1887.Google Scholar
  60. 60.
    Shkolin, A.V. and Fomkin, A.A., Protection of Metals and Physical Chemistry of Surfaces., 2016, vol. 52, p. 193.CrossRefGoogle Scholar
  61. 61.
    Kowalczyk, P., Ciach, A., and Neimark, A.V., Langmuir, 2008, vol. 24, p. 6603.CrossRefGoogle Scholar
  62. 62.
    Anuchin, K.M., Fomkin, A.A., Korotich, A.P., and Tolmachev, A.M., Protection of Metals and Physical Chemistry of Surfaces, 2014, vol. 50, p. 173.CrossRefGoogle Scholar
  63. 63.
    Dubinin, M.M., Fomkin, A.A., Seliverstova, I.I., and Serpinsky, V.V., Abstracts of Papers, 5 Int. Conf. on Zeolites, Napoli, Italy, 1980, p. 468.Google Scholar
  64. 64.
    Novikova, S.I., Teplovoe rasshirenie tverdykh tel (Thermal Expansion of Solids), Moscow: Nauka, 1974.Google Scholar
  65. 65.
    Tekhnicheskaya entsiklopediya. Spravochnik fizicheskikh, khimicheskikh i tekhnologicheskikh velichin. T. 5 (Technical Encyclopedia. Handbook of Physical, Chemical, and Technological Quantities. Vol. 5), Berkengeim, B.M., Ed., Moscow: AO “Sovetskaya entsiklopediya”, 1930.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. A. Fomkin
    • 1
  • A. V. Shkolin
    • 1
  • A. L. Pulin
    • 1
  • I. E. Men’shchikov
    • 1
  • E. V. Khozina
    • 1
  1. 1.Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussia

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