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Russian Journal of Electrochemistry

, Volume 54, Issue 11, pp 949–955 | Cite as

Adsorption of Serine Anion on Smooth and Platinized Platinum

  • N. E. Kuleshova
  • A. V. VvedenskiiEmail author
  • E. V. Bobrinskaya
Article
  • 3 Downloads

Abstract

The adsorption of serine anion on a smooth and platinized platinum electrode is investigated. The stationary and kinetic adsorption isotherms are plotted. For both smooth platinum electrodes and Pt(Pt) electrodes, the kinetics of the processes under investigation obeys the Roginsky–Zeldovich equation, and the stationary coverage is described by the Temkin isotherm. The main thermodynamic characteristics (adsorption equilibrium constant and change in the Gibbs free energy) of the process of adsorption of serine anion on both electrodes are found.

Keywords

serine amino acid platinum adsorption isotherm 

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References

  1. 1.
    Damaskin, B.B., Electrode Processes in Solutions of Organic Compounds, Moscow: Mosk. Gos. Univ., 1985.Google Scholar
  2. 2.
    Sobkowski, J. and Juzkiewics-Herbish, M., Metall/solution interface: an experimental approach, in Modern Aspects of Electrochemistry, no. 31, Bockris, J.O’M., White, R.E., and Conway, B.E., Eds., New York: Plenum, 1997.Google Scholar
  3. 3.
    Frumkin, A.N., Selected Works: Electrode Processes, Moscow: Nauka, 1987.Google Scholar
  4. 4.
    Delahay, P., Double Laver and Electrode Kinetics, NewYork: Interscience, 1965.Google Scholar
  5. 5.
    Gileadi, E., Intermediates in electrode reactions, in Electrode Kinetics for Chemists, Chemical Engineers and Materials Scientists, New York: Wiley, 1993, p. 261.Google Scholar
  6. 6.
    Electrocatalysis, Lipkowski, J. and Ross, P.N., Eds., Chichester: Wiley, 1998.Google Scholar
  7. 7.
    Bockris, J.O’M., Shahed, U., and Khan, M., Surface Electrochemistry: A Molecular Level Approach, NewYork: Plenum, 1993.s f fCrossRefGoogle Scholar
  8. 8.
    Smith, A., Applied Infrared Spectroscopy, New York: Wiley, 1979.Google Scholar
  9. 9.
    Gale, J., Spectroelectrochemistry: Theory and Practice, New York: Plenum, 1988.CrossRefGoogle Scholar
  10. 10.
    Tekhnika eksperimental’nykh rabot po elektrokhimii, korrozii i poverkhnostnoi obrabotke metallov (Technique of Experimental Work on Electrochemistry, Corrosion, and Surface Treatment of Metals), Kun, A.T., Ed., St. Petersburg: Khimiya, 1994, vol. 1.Google Scholar
  11. 11.
    Lasia, A., Electrochemical Impedance Spectroscopy and Its Application, New York: Springer, 1999.Google Scholar
  12. 12.
    Yeager, E.B., Techniques of Electrochemistry, Yeager, E.B. and Salkind, A.J., Eds., New York: Wiley, 1972, vol. 1.Google Scholar
  13. 13.
    Theory of Chemisorption, Smith, J., Ed., Berlin: Springer, 1980.Google Scholar
  14. 14.
    Horányi, G., Study of the adsorption of glycine on platinized platinum electrodes by tracer methods, J. Electroanal. Chem., 1975, vol. 64, nos. 1–2, p. 15.Google Scholar
  15. 15.
    Huerta, F., Morallon, E., Cases, F., Rodes, A., Vázquez, J.L., and Aldaz, A., Electrochemical behaviour of amino acids on Pt(h,k,l): A voltammetric and in situ FTIR study. Part 1. Glycine on Pt(111), J. Electroanal. Chem., 1997, vol. 421, nos. 1–2, p. 179.Google Scholar
  16. 16.
    Huerta, F., Morallon, A., Vázquez, J.L., Pérez, J.M., and Aldaz, A., Electrochemical behaviour of amino acids on Pt(h,k,l): A voltammetric and in situ FTIR study. Part III. Glycine on Pt(100) and Pt(110), J. Electroanal. Chem., 1998, vol. 445, nos. 1–2, p. 155.Google Scholar
  17. 17.
    Huerta, F., Morallon, A., Vázquez, J.L, Quijada, C., and Berlouis, L., Potential modulated reflectance study of the electrooxidation of simple amino acids on Pt(111) in acidic media, J. Electroanal. Chem., 2000, vol. 489, p. 92.CrossRefGoogle Scholar
  18. 18.
    Shi-Gang Sun, Jian-Lin Yao, Qi-Hui Wu, and Zhong-Qun Tian, Surface-enhanced Raman spectroscopic studies of dissociative adsorption of amino acids on platinum and gold electrodes in alkaline solutions, Langmuir, 2002, vol. 18, p. 6274.Google Scholar
  19. 19.
    Tumanova, E.A. and Safonov, A.Yu., Adsorption of some amino acids and dipeptides at the platinum electrode, Russ. J. Elektrokhem., 1998, vol. 34, no. 2, p. 153.Google Scholar
  20. 20.
    Marangoni, D.G., Smith, R.S., Roscoe, S.G., and Marangoni, D.G., Surface electrochemistry of the oxidation of glycine at a platinum electrode, Can. J. Chem., 1989, vol. 67, p. 921.CrossRefGoogle Scholar
  21. 21.
    Ogura, K., Kobayashi, M., Nakayama, M., and Miho, M., Electrochemical and in-situ FTIR studies on the adsorption and oxidation of glycine and lysine in alkaline medium, J. Electroanal. Chem., 1998, vol. 449, p. 101.CrossRefGoogle Scholar
  22. 22.
    Gu, Y.J., Chen, S.P., Sun, S.G., and Zhou, Z.Y., Adsorption of serine on Pt single-crystal electrodes in sulfuric acid solutions, Langmuir, 2003, vol. 19, p. 9823.CrossRefGoogle Scholar
  23. 23.
    Huerta, F., Morallon, E., Cases, F., Rodes, A., Vázquez, J.L., and Aldaz, A., Electrochemical behaviour of amino acids on Pt(h,k,l): A voltammetric and in situ FTIR study. Part II. Serine and alanine on Pt(111), J. Electroanal. Chem., 1997, vol. 431, p. 269.CrossRefGoogle Scholar
  24. 24.
    Huerta, F., Morallon, E., Vázquez, J.L., and Aldaz, A., Electrochemical behaviour of amino acids on Pt(h,k,l): A voltammetric and in situ FTIR study. Part IV. Serine and alanine on Pt(100) and Pt(110), J. Electroanal. Chem., 1999, vol. 475, p. 38.CrossRefGoogle Scholar
  25. 25.
    Horanyi, G., A direct and indirect radiotracer study of the adsorption of serine at a platinized platinum electrode, J. Electroanal. Chem., 1991, vol. 304, p. 211.CrossRefGoogle Scholar
  26. 26.
    Kong De-Wen, Zhu Tian-Wei, Zeng Dong-Mei, Zhen Chun-Hua, Chen Sheng-Pei, and Sun Shi-Gan, Insitu FTIR spectroscopic studies of adsorption and oxidation of L-serine on Pt electrodes in neutral solutions, Chem. J. Chin. Univ., 2009, vol. 30, no. 10, p. 2040.Google Scholar
  27. 27.
    Safonova, T.Yu., Khidirov, Sh.Sh., and Petrii, O.A., Adsorption and electro-oxidation of some amino acids containing a hydroxyl group on a platinized platinum electrode, Elektrokhimiya, 1984, vol. 20, no. 12, p. 1666.Google Scholar
  28. 28.
    Damaskin, B.B., Petrii, O.A., and Tsyrlina, G.A., Electrokhimiya (Electrochemistry), Moscow: Khimiya, 2001.Google Scholar
  29. 29.
    Damaskin, B.B. and Petrii, O.A., Vvedenie v electrokhimiceskyu kinetiku (Introduction to Electrochemical Kinetics), Moscow: Vysshaya Shkola, 1983.Google Scholar
  30. 30.
    Frumkin, A.N., Bagotskii, V.S., Iofa, Z.A. and Kabanov, B.N., Kinetika elektrodnyh processov (Kinetics of Electrode Processes), Moscow: Mosk. Gos. Univ., 1952.Google Scholar
  31. 31.
    Kuleshova, N.E., Vvedenskii, A.V., and Bobrinskaya, E.V., Anodic oxidation of serin anion on smooth and platinized platinum, Russ. J. Electrochem., 2018, vol. 54, no. 7, p. 592.CrossRefGoogle Scholar
  32. 32.
    Frumkin, A.N. and Podlovchenko, B.I., On the nature of the potentials of a platinum electrode arising in ethanol solutions, Dokl. Akad. Nauk SSSR, 1963, vol. 150, no. 2, p. 349.Google Scholar
  33. 33.
    Podlovchenko, B.I. and Iofa, Z.A., On chemisorption of ethanol and acetaldehyde on platinum and the effect of background anions on it, Zh. Fiz. Khim., 1964, vol. 38, no. 1, p. 211.Google Scholar
  34. 34.
    Bobrinskaya, E.V., Vvedenskii, A.V., Kartashova, T.V., and Krashenko, T.G., Analysis of liquid-phase adsorption involving the generalized isotherm formalism. Part1. Thermodynamics and kinetics of the process, Korroz.: Mater., Zashch., 2013, no. 8, p. 1.Google Scholar
  35. 35.
    Bragin, O.V. and Liberman, A.L., Stereochemistry of certain catalytic reactions of cyclic hydrocarbons in the presence of Group VIII noble metals, Russ. Chem. Rev., 1970, vol. 39, p. 1017.CrossRefGoogle Scholar
  36. 36.
    Anderson, I.R., Macdonald, R.I., and Shimoyama, Y., Relation between catalytic properties and structure of metal films: II. Skeletal reactions of some C6 alkanes, J. Catal., 1971, vol. 20, no. 2. p. 147.Google Scholar
  37. 37.
    Levitskii, I.L. and Minachev, Kh.M., in Mechanisms of Hydrocarbon Reactions: A Symposium, Márta, F. and Kalló, D., Budapest: Academiai Kiado, 1975.Google Scholar
  38. 38.
    Anderson, J.R. and Baker, B.G., Catalytic reactions on metal films, in Chemisorption and Reactions on Metallic Films, Anderson, J.R., Ed., New York: Academic, 1971, p. 63.Google Scholar
  39. 39.
    Bragin, O.V., Preobrazenskii, A.V., Liberman, A.L., and Kazanskii, B.A., On the difference in the mechanisms of C5 and C6 dehydrocyclization of alkanes in the presence of platinized coal, Kin. Kat., 1975, vol. 16, no. 2, p. 472.Google Scholar
  40. 40.
    Maire, G., Corolleur, C., Juttard, D., and Gault, F.G., Comments on a dispersion effect in hydrogenolysis of methylcyclopentane and isomerization of hexanes over supported platinum catalysts, J. Catal., 1971, vol. 21, no. 2, p. 250.CrossRefGoogle Scholar
  41. 41.
    Corolleur, C., Corolleur, S., and Gault, F.G., The mechanisms of hydrogenolysis and isomerization of hydrocarbons on metals. VI. Isomerization of labeled hexanes on a 0.2% platinum–alumina catalyst, J. Catal., 1972, vol. 24, no. 3, p. 385.CrossRefGoogle Scholar
  42. 42.
    Paal, Z. and Tetenyi, P., C5-cyclization of unsaturated hydrocarbons on platinum black, Acta Chim. Acad. Sci. Hung., 1972, vol. 72, no. 3, p. 277.Google Scholar
  43. 43.
    Barron, Y., Maire, G., Muller, J.M., and Gault, F.G., The mechanisms of hydrogenolysis and isomerization of hydrocarbons on metals: II. Mechanisms of isomerization of hexanes on platinum catalysts, J. Catal., 1966, vol. 5, no. 3, p. 428.CrossRefGoogle Scholar
  44. 44.
    Muller, J.M. and Gault, F.G., Mechanisms of dehydrocyclization on platinum and palladium catalysts, J. Catal., 1972, vol. 24, no. 2, p. 361.CrossRefGoogle Scholar
  45. 45.
    Contreras, A.M., Grunes, J., Yan, X.-M., Liddle, A.G., and Somorjai, A., Fabrication of 2-dimensional platinum nanocatalyst arrays by electron beam lithography: Ethylene hydrogenation and CO-poisoning reaction studies, Top. Catal., 2006, vol. 39, nos. 3–4, p. 123.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • N. E. Kuleshova
    • 1
  • A. V. Vvedenskii
    • 1
    Email author
  • E. V. Bobrinskaya
    • 1
  1. 1.Voronezh State UniversityVoronezhRussia

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