Russian Journal of Electrochemistry

, Volume 54, Issue 3, pp 318–323 | Cite as

New Composite Proton-Conducting Membranes Based on Nafion and Cross-Linked Sulfonated Polystyrene

  • A. A. Arslanova
  • E. A. Sanginov
  • Yu. A. Dobrovol’skii
Short Communications
  • 9 Downloads

Abstract

New composite membranes based on commercial perfluorinated Nafion-115 membrane and cross-linked sulfonated polystyrene were synthesized and investigated. The membranes were prepared by radical polymerization of styrene in the presence of a cross-linking agent divinylbenzene in Nafion polymer matrix and subsequent sulfonation of formed polystyrene. The membranes containing approximately 5 and 10 wt % of cross-linked polystyrene with ion-exchange capacity of 1.1 to 1.3 mg-eq/g were obtained. Modification with sulfonated polystyrene leads to an increase in the moisture content and proton conductivity of membranes in the humidity range of 15 to 100 RH.

Keywords

proton-conducting membranes Nafion composites sulfonated polystyrene proton conductivity 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. A. Arslanova
    • 1
    • 2
  • E. A. Sanginov
    • 1
  • Yu. A. Dobrovol’skii
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovkaRussia
  2. 2.Faculty of Fundamental Physical and Chemical EngineeringMoscow State UniversityMoscowRussia

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