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Polymer Science, Series A

, Volume 60, Issue 6, pp 828–844 | Cite as

Hybrid Materials Based on Na Liquid Glass, 2,4-Toluene Diisocyanate, Epoxy Oligomer, and Polyisocyanate

  • A. P. PustovgarEmail author
  • M. G. Bruyako
  • M. D. Petunova
  • E. S. Afanasyev
  • M. G. Ezernitskaya
  • M. V. Starozhitskii
  • K. S. Piminova
  • T. A. Matseevich
  • A. A. Askadskii
Composites

Abstract

The relaxation properties of hybrid organomineral composite materials based on sodium liquid glass, 2,4-toluene diisocyanate, and polyisocyanate modified with epoxide resin are studied by spectral methods and concomitant calculations. It is demonstrated that chemical transformations occurring under heating during preparation of monolithic samples follow a complex pattern. Upon modification of the initial blends with the epoxy-diane resin, the composite acquires a homogeneous granular structure and its mechanical properties are improved. The initial relaxation moduli are as high as 1000 and 540 MPa at 20 and 100°С, respectively. For unmodified materials, the initial relaxation moduli are 730 and 520 MPa at 20 and 100°С, respectively. Master relaxation curves making it possible to forecast relaxation behavior under prolonged relaxation are obtained. The material containing the highest amount of polyisocyanate shows an extremely high relaxation modulus.

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References

  1. 1.
    M. A. Meador, E. F. Fabrizio, F. Ilhan, A. Dass, G. Zhang, P. Vassilarias, J. C. Johnston, and N. Leventis, J. Chem. Mater. 17, 1085 (2005).CrossRefGoogle Scholar
  2. 2.
    D. J. Boday and D. A. Loy, Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 50, 282 (2009).Google Scholar
  3. 3.
    D. M. Delozier, R. A. Orwoll, J. F. Cahoon, J. S. Ladislaw, J. G. Smith, and J. W. Connell, Polymer 44 (8), 2231 (2003).CrossRefGoogle Scholar
  4. 4.
    A. K. Khripunov, Yu. G. Baklagina, V. A. Sinyaev, E. S. Shustikova, B. A. Paramonov, D. P. Romanov, R. Yu. Smyslov, and A. A. Tkachenko, Glass Phys. Chem. 34 (2), 192 (2008).CrossRefGoogle Scholar
  5. 5.
    Y. Z. Wan, L. Hong, S. R. Jia, Y. Huang, Y. Zhu, Y. L. Wang, and H. J. Jiang, Comp. Sci. Technol 66, 1825 (2006).CrossRefGoogle Scholar
  6. 6.
    V. I. Roldugin, O. A. Serenko, E. V. Getmanova, N. A. Karmishina, S. N. Chvalun, and A. M. Muzafarov, Dokl. Phys. Chem. 449 (2), 83 (2013).CrossRefGoogle Scholar
  7. 7.
    A. S. Zhil’tsov, I. B. Meshkov, T. S. Kurkin, O. B. Gorbatsevich, V. V. Kazakova, A. A. Askadskii, O. A. Serenko, A. N. Ozerin, and A. M. Muzafarov, Nanotechnol. Russ. 8 (9–10), 644 (2013).CrossRefGoogle Scholar
  8. 8.
    A. D. Pomogailo, Ross. Khim. Zh. 56 (5), 64 (2002).Google Scholar
  9. 9.
    V. A. Gerasin, E. M. Antipov, V. V. Karbushev, V. G. Kulichikhin, G. P. Karpacheva, R. V. Tal’roze, and Ya. V. Kudryavtsev, Russ. Chem. Rev. 82 (4), 303 (2013).CrossRefGoogle Scholar
  10. 10.
    A. V. Povolotskaya, A. V. Povolotskii, and A. A. Man’shina, Russ. Chem. Rev. 84 (6), 579 (2015).CrossRefGoogle Scholar
  11. 11.
    Z. Ge and Y. Luo, Prog. Org. Coat. 76 (11), 1522 (2013).CrossRefGoogle Scholar
  12. 12.
    H. Sardon, L. Irusta, M. J. Fernandez-Berridi, M. Lansalot, and E. Bourgeat-Lami, Polymer 51, 5051 (2010).CrossRefGoogle Scholar
  13. 13.
    K. Szwarc-Rzepka, T. Szatkowski, F. Ciesielczyk, and T. Jesionowski, Physicochem. Probl. Miner. Process. 49 (2), 673 (2013).Google Scholar
  14. 14.
    A. Rekondo, M. J. Fernaґndez-Berridi, and L. Irusta, Eur. Polym. J. 42, 2069 (2006).CrossRefGoogle Scholar
  15. 15.
    M. S. Shabalina, E. A. Antipova, and G. A. Khlebov, Kauch. Rezina, No. 5, 26 (2014).Google Scholar
  16. 16.
    A. A. Askadskii, Computational Materials Science of Polymers (Cambridge Int. Sci. Publ., Cambridge, 2003).Google Scholar
  17. 17.
    A. A. Askadskii and V. I. Kondrashchenko, Computer Materials Science of Polymers (Nauchnyi mir, Moscow, 1999), Vol. 1 [in Russian].Google Scholar
  18. 18.
    A. A. Askadskii and A. R. Khokhlov, Introduction to Polymer Physics and Chemistry (Nauchnyi mir, Moscow, 2009) [in Russian].Google Scholar
  19. 19.
    A. A. Askadskii, S. A. Tishin, V. V. Kazantseva, and O. V. Kovriga, Vysokomol. Soedin., Ser. A 32 (12), 2437 (1990).Google Scholar
  20. 20.
    A. A. Askadskii, S. A. Tishin, M. I. Tsapovetskii, V. V. Kazantseva, O. V. Kovriga, and V. A. Tishin, Vysokomol. Soedin., Ser. A 34 (1), 62 (1992).Google Scholar
  21. 21.
    R. J. Gaylord, B. Joss, J. T. Bendler, and E. A. Di Marzio, Br. Polym. J. 17 (2), 126 (1985).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. P. Pustovgar
    • 1
    Email author
  • M. G. Bruyako
    • 1
  • M. D. Petunova
    • 2
  • E. S. Afanasyev
    • 2
  • M. G. Ezernitskaya
    • 2
  • M. V. Starozhitskii
    • 2
  • K. S. Piminova
    • 2
  • T. A. Matseevich
    • 1
  • A. A. Askadskii
    • 1
    • 2
  1. 1.Moscow State University of Civil EngineeringMoscowRussia
  2. 2.Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia

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