Hydroconversion of Vacuum Residue of a Blend of Western Siberian Oils in the Presence of Ex Situ Synthesized Suspensions of Nanosized Catalysts

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Concentrated suspensions of nanosized МоS2, МоS2+Ni7S6, Ni7S6, Fe1– xS, and (NH4)0.25 · WO3 particles with an average size of 273–364 nm have been synthesized from reverse emulsions of aqueous solutions of molybdenum, nickel, iron, and tungsten salts in the presence of a sulfiding agent and hydrogen in oil vacuum distillation residues and tested in oil vacuum distillation residue hydroconversion running in an autoclave and a pilot flow system. The test results have shown that the highest activity in hydrogenolysis reactions is exhibited by Mo-containing catalysts. The kinetic characteristics have been determined; the heat of the hydroconversion process has been calculated.

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  1. 1

    D. Gillis, M. van Wees, and P. Zimmerman, in Proceedings of Annual Meeting of National Petrochemical and Refiners Association, March 22–24,2009, San Antonio. TX, AM-09-65, p. 15. http://virtu- what_we_do/web/assets/UOP_EMEA_Conference/ pdfs/Papers/Uniflex.pdf.

  2. 2

    D. L. Stratiev, I. N. Shishkova, R. N. Dinkov, et al., Neftegazokhimiya, No. 1, 3 (2014).

  3. 3

    O. F. Glagoleva, Mir Nefteprod., No. 5, 3 (2008).

  4. 4

    A. A. Chuvasova, in Proceedings of VII International Scientific Conference, Krasnodar, February 2017 (Novatsiya, Krasnodar, 2017), p. 114 [in Russian].

  5. 5

    V. Galkin, V. Makhiyanov, and M. Levinbuk, Oil Gas J. Russ., No. 3, 67 (2014).

  6. 6

    V. Kapustin, E. Chernysheva, and E. Timin, Oil Gas J. Russ., No. 8, 80 (2018).

  7. 7

    S. N. Khadzhiev, Pet. Chem. 56, 465 (2016).

  8. 8

    S. Zhang, D. Liu, W. Deng, and G. Que, Energy Fuels 21, 3057 (2007).

  9. 9

    M. S. Rana, V. Saґmano, J. Ancheyta, and J. A. I. Diaz, Fuel 86, 1216 (2007).

  10. 10

    S. N. Khadzhiev and Kh. M. Kadiev, Chem. J., No. 9, 34 (2009).

  11. 11

    J. Yves and M. Davidson, and J. F. Le Page, US Patent No. 4285804 (1981).

  12. 12

    R. K. Lott, in Proceedings of 7th UNITAR International Conference on Heavy Crude and Tar Sand, Beijing (Petroleum Industry Press, Beijing, 1998).

  13. 13

    G. Bellussi, G. Rispoli, A. Landoni, et al., J. Catal. 308, 189 (2013).

  14. 14

    Kh. M. Kadiev, S. N. Khadzhiev, M. Kh. Kadieva, and E. S. Dogova, Pet. Chem. 57, 608 (2017).

  15. 15

    A. L. Maksimov, L. A. Zekel’, M. Kh. Kadieva, et al., Pet. Chem. 59, 968 (2019).

  16. 16

    Kh. M. Kadiev, N. V. Oknina, A. L. Maksimov, et al., Res. J. Pharm. Biol. Chem. Sci. 7, 704 (2016).

  17. 17

    Kh. M. Kadiev, L. A. Zekel’, M. Kh. Kadieva, and S. N. Khadzhiev Pet. Chem. 58, 519 (2018).

  18. 18

    S. G. Jeon, J.-G. Na, C. H. Ko, et al., Energy Fuels 25, 4256 (2011).

  19. 19

    J. Ancheyta, F. Treiro, and M. S. Rana, Asphaltenes: Chemical Transformation during Hydroprocessing of Heavy Oils (CRC, Boca Raton, 2009).

  20. 20

    A. Y. León, A. Guzman, D. Laverde, et al., Energy Fuels 31, 3868 (2017).

  21. 21

    D. Stull, E. Westrum, and G. Sinke, The Chemical Thermodynamics of Organic Compounds (Wiley, New York, 1969).

  22. 22

    A. M. Gyulmaliev, V. P. Popova, I. I. Romantsova, and A. A. Krichko, Fuel 71, 1329 (1992).

  23. 23

    Kh. M. Kadiev, A. M. Gyul’maliev, and N. A. Kubrin, Pet. Chem. 56, 807 (2016).

  24. 24

    N. B. Vargaftik, Handbook of Thermal Properties of Gases and Liquids (Stars, Moscow, 2006) [in Russian].

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Correspondence to L. A. Zekel’.

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Translated by M. Timoshinina

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Kadiev, K.M., Gyul’maliev, A.M., Zekel’, L.A. et al. Hydroconversion of Vacuum Residue of a Blend of Western Siberian Oils in the Presence of Ex Situ Synthesized Suspensions of Nanosized Catalysts. Pet. Chem. 59, S37–S44 (2019) doi:10.1134/S0965544119130061

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  • oil vacuum distillation residue
  • dispersed catalysts
  • hydrocracking