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Theoretical Foundations of Chemical Engineering

, Volume 53, Issue 5, pp 875–879 | Cite as

The Development of a Method for the Production of Structural Polymeric Materials on the Basis of Norbornene Derivatives

  • G. S. BozhenkovaEmail author
  • N. A. Smirnova
  • O. O. Bragina
  • R. V. Ashirov
TECHNOLOGY OF POLYMERIC AND COMPOSITE MATERIALS
  • 8 Downloads

Abstract

Process parameters of the polymerization of a mixture of exo,exo- and endo,endo-dimethyl esters of norbornene-2,3-dicarboxylic acid in the bulk of the monomer under the action of a ruthenium catalyst of the Hoveyda–Grubbs type are developed. The effect of the concentration of the catalyst on the physical and mechanical properties of poly(norbornene-2,3-dicarboxylic acid dimethyl ester) is studied.

Keywords:

norbornene derivatives ruthenium catalyst ring-opening metathesis polymerization 

Notes

REFERENCES

  1. 1.
    Savin, S.P., The use of up-to-date polymeric composite materials in the design of airframes for MS-21 airplanes, Izv. Samar. Nauchn. Tsentra Ross. Akad. Nauk, 2012, vol. 14, no. 4 (2), pp. 686–693.Google Scholar
  2. 2.
    Yang, J.-X., Cui, J., Long, Y.-Y., Li, Y.-G., and Li, Y.-S., Synthesis of novel cyclic olefin polymers with excellent transparency and high glass-transition temperature via gradient copolymerization of bulky cyclic olefin and cis-cyclooctene, J. Polym. Sci., Part A: Polym. Chem., 2014, vol. 52, no. 22, pp. 3240–3249. https://doi.org/ 10.1002/pola.27386CrossRefGoogle Scholar
  3. 3.
    Hobbs, C.E., Lin, B., and Malinski, T., Norbornene derivatives from a metal-free, strain-promoted cycloaddition reaction: New building blocks for ring-opening metathesis polymerization reactions, J. Polym. Sci., Part A: Polym. Chem., 2015, vol. 53, no. 20, pp. 2357–2362. https://doi.org/10.1002/pola.27691CrossRefGoogle Scholar
  4. 4.
    Mol, J.C., Industrial applications of olefin metathesis, J. Mol. Catal. A: Chem., 2004, vol. 213, no. 1, pp. 39–45. https://doi.org/10.1016/j.molcata.2003.10.049CrossRefGoogle Scholar
  5. 5.
    Gurevich, P.A., Zemlyakov, D.I., Bozhenkova, G.S., and Ashirov, R.V., Effect of ethylene glycol-dinorbornene-5-carboxylate on the glass transition temperature of a polymer based on the dimethyl ethers of exo- and endo-norbornene-2,3-dicarboxylic acids, Vestn. Kazan. Tekhnol. Univ., 2013, vol. 16, no. 11, pp. 155–157.Google Scholar
  6. 6.
    Zamanova, M.K., Bozhenkova, G.S., Bondaletov, V.G., Samochernova, A.P., and Zemlyakov, D.I., Analytical control for the production of exo,exo- and endo,endo-dimethyl ethers of norbornene-2,3-dicarboxylic acid, Sorbtsionnye Khromatogr. Protsessy, 2016, vol. 16, no. 2, pp. 241–250.Google Scholar
  7. 7.
    Afanas’ev, V.V., Nizovtsev, A.V., Dolgina, T.M., and Bespalova, N.B., RF Patent 2374269, 2009.Google Scholar
  8. 8.
    Jang, E.S., John, J.M., and Schrock, R.R., Synthesis of cis,syndiotactic A-alt-B copolymers from two enantiomerically pure trans-2,3-disubstituted-5,6-norbornenes, ACS Cent. Sci., 2016, vol. 2, no. 9, pp. 631–636. https://doi.org/10.1021/acscentsci.6b00200Google Scholar
  9. 9.
    Gurevich, P.A., Bozhenkova, G.S., Zemlyakov, D.I., and Ashirov, R.V., Effect of a bifunctional comonomer on the physicomechanical properties of a polymer based on polydimethyl-norbornene-2,3-dicarboxylates, Vestn. Kazan. Tekhnol. Univ., 2015, vol. 18, no. 2, pp. 227–230.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • G. S. Bozhenkova
    • 1
    Email author
  • N. A. Smirnova
    • 1
  • O. O. Bragina
    • 1
  • R. V. Ashirov
    • 2
  1. 1.National Research Tomsk Polytechnic UniversityTomskRussia
  2. 2.AO PolyusKrasnoyarskRussia

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