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Russian Journal of Physical Chemistry A

, Volume 93, Issue 11, pp 2275–2283 | Cite as

Amino Acid Adsorption on Surfaces of Brushite and Hydroxylapatite

  • O. A. GolovanovaEmail author
  • K. K. Golovchenko
PHYSICAL CHEMISTRY OF SURFACE PHENOMENA
  • 6 Downloads

Abstract

Amino acid adsorption on surfaces of brushite and hydroxylapatite (HA) is studied at different solution pH and amino acid concentration values. The synthesis of HA and brushite is conducted; the composition of the solid phases is confirmed by X-ray diffraction, IR spectroscopy, and optical microscopy. The specific surface area of brushite (9.0 m2/g) and HA (72.0 m2/g) is determined by the BET method. The effect of the solution pH on the maximum adsorption of amino acids on brushite and HA is revealed. To determine the adsorption mechanism, the sign of the surface charge of the solid phase of brushite and HA (positive) is determined by capillary analysis. The Gibbs free energy values are calculated. It is assumed that amino acids interact with the surface of brushite and HA in accordance with the physical adsorption mechanism.

Keywords:

brushite hydroxylapatite adsorption amino acid 

Notes

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Dostoevsky Omsk State UniversityOmskRussia

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