Advertisement

Russian Journal of Physical Chemistry A

, Volume 93, Issue 8, pp 1489–1496 | Cite as

Physical Properties of Butyronitrile Mixtures with Pentane, Hexane, Heptane, and Octane

  • D. VenkatesanEmail author
  • D. Joshua Amarnath
  • E. Sinduri
  • K. Saravanakumar
PHYSICAL CHEMISTRY OF SOLUTIONS
  • 8 Downloads

Abstract

Experimental results on density and viscosity of binary mixtures of butyronitrile with pentane, hexane, heptane, and octane are presented at 298.15, 303.15, 308.15 K and atmospheric pressure over the whole mixture composition scale 0 to 1. From these data, excess molar volume VE, deviation in viscosity ∆η and excess Gibb’s free energy of activation flow ∆G*E have been calculated. The viscosity data were correlated with Grunberg–Nissan, Hind and KendallMonroe models.

Keywords:

density viscosity butyronitrile excess properties molecular interactions 

Notes

ACKNOWLEDGMENTS

I express my sincere gratitude to the management of Sathyabama Institute of Science and Technology for availing research facilities to carry out and publish this work.

DECLARATION OF INTEREST

There is no conflict of interest.

REFERENCES

  1. 1.
    J. Balan, Moravkova, and J. Linek, Chem. Pap. 61, 497 (2007).CrossRefGoogle Scholar
  2. 2.
    G. Bolat, G. Lisa, and I. M. Popa, Sci. Study Res. 6, 181 (2005).Google Scholar
  3. 3.
    K. Saravanakumar, T. G. Lavanya, R. Baskaran, and T. R. Kubendran, Russ. J. Phys. Chem. A 86, 647 (2012)Google Scholar
  4. 4.
    K. Saravanakumar, T. G. Lavanya, R. Baskaran, and T. R. Kubendran, Russ. J. Phys. Chem. A 86, 568 (2012)CrossRefGoogle Scholar
  5. 5.
    B. Orge M. Iglesias, A. Rodríguez, J. M. Canosa, and J. Tojo, Fluid Phase Equilib. 133, 213 (1997).Google Scholar
  6. 6.
    M. I. Aralaguppi, C. V. Jadar, and T. M. Aminabhavi, J. Chem. Eng. Data 44, 446 (1999)CrossRefGoogle Scholar
  7. 7.
    E. Kovacs, K. Aim, and J. Linek, J. Chem. Thermodyn. 33, 33 (2001).CrossRefGoogle Scholar
  8. 8.
    J. Nath and J. Gopal Pandey, J. Chem. Eng. Data 42, 1133 (1997).CrossRefGoogle Scholar
  9. 9.
    N. V. Sastry and M. M. Raj, J. Chem. Eng. Data 41, 612 (1996).CrossRefGoogle Scholar
  10. 10.
    G. P. Dubey and M. Sharma, J. Chem. Eng. Data 52, 449 (2007).CrossRefGoogle Scholar
  11. 11.
    A. Estrada-Baltazar, G. A. Iglesias-Silva, and C. Caballero-Cerón, J. Chem. Eng. Data 58, 3351 (2013).CrossRefGoogle Scholar
  12. 12.
    A. R. Neale, Ch. Schütter, P. Wilde, P. Goodrich, Ch. Hardacre, S. Passerini, A. Balducci, and J. Jacquemin, J. Chem. Eng. Data 62, 376 (2017).CrossRefGoogle Scholar
  13. 13.
    H. Iloukhani and M. Rezaei-Sameti, J. Chem. Eng. Data 50, 1928 (2005).CrossRefGoogle Scholar
  14. 14.
    M. A. Postigo, J. L. Zurita, M. L. G. de Soria, and M. Katz, Can. J. Chem. 64, 1966 (1986).CrossRefGoogle Scholar
  15. 15.
    R. Tahery, J. Chem. Thermodyn. 106, 95 (2017).CrossRefGoogle Scholar
  16. 16.
    O. Redlich and A. T. Kister, Ind. Eng. Chem. 40, 345 (1948).CrossRefGoogle Scholar
  17. 17.
    A. B. Pereiro and A. Rodriguez, J. Chem. Thermodyn. 39, 1219 (2007).CrossRefGoogle Scholar
  18. 18.
    A. A. S. M. Zahid, M. A. Ali, and J. R. Hahn, Adv. Appl. Sci. Res. 6 (6), 65 (2015).Google Scholar
  19. 19.
    M. Dzida and P. Goralski, J. Chem. Thermodyn 38, 962 (2006).CrossRefGoogle Scholar
  20. 20.
    C. Guzman, C. Lafuente, J. Santafe, F. M. Royo, and J. S. Urieta, Int. J. Thermophys. 20, 1435 (1999).CrossRefGoogle Scholar
  21. 21.
    C. Franjo, E. Jiménez, T. P. Iglesias, J. L. Legido, and M. I. Paz Andrade, J. Chem. Eng. Data 40, 68 (1995).CrossRefGoogle Scholar
  22. 22.
    I. R. Radovic, M. Lj. Kijevcanin, M. Z. Gabrijel, S. P. Serbanovic, and B. D. Djordjevic, Chem. Pap. 62, 302 (2008).CrossRefGoogle Scholar
  23. 23.
    S. L. Oswal, J. P. Dave, and I. N. Patel, Int. J. Thermophys. 20, 1449 (1999).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • D. Venkatesan
    • 1
    Email author
  • D. Joshua Amarnath
    • 1
  • E. Sinduri
    • 1
  • K. Saravanakumar
    • 2
  1. 1.Department of Chemical Engineering, Sathyabama Institute of Science and TechnologyChennaiIndia
  2. 2.Department of Engineering, College of Applied Sciences, SoharMoHEOman

Personalised recommendations