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Russian Journal of Physical Chemistry A

, Volume 93, Issue 8, pp 1567–1571 | Cite as

Triple Complexes of Bismuth Nanoparticles with β-Cyclodextrin and Polyvinylpyrrolidone

  • I. V. PolyakovaEmail author
  • L. N. Borovikova
  • E. M. Korotkikh
  • A. I. Kipper
  • O. A. Pisarev
PHYSICAL CHEMISTRY OF NANOCLUSTERS AND NANOMATERIALS
  • 4 Downloads

Abstract

Ternary complexes of bismuth nanoparticles with β-cyclodextrin and polyvinylpyrrolidone are studied via UV and visible spectroscopy and dynamic light scattering. It is shown that, depending on the ratio of the concentrations of β-cyclodextrin to polyvinylpyrrolidone in a synthetic medium, bismuth nanoparticles can be stabilized sterically either by distributing polyvinylpyrrolidone molecules over the surface of a complex of nanoparticles with β-cyclodextrin or by forming inclusion complexes of nanoparticles in the hydrophobic cavity of β-cyclodextrin as a result of associated β-cyclodextrin molecules being pushed apart by polyvinylpyrrolidone molecules. The conditions are determined for the formation of ternary complexes that are aggregatively stable for 20 days and are characterized by a unimodal particle size distribution.

Keywords:

nanoparticle synthesis bismuth β-cyclodextrin polyvinylpyrrolidone aggregative stability 

Notes

ACKNOWLEDGMENTS

This work was supported by the Russian Foundation for Basic Research, project no. 18-03-00835.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • I. V. Polyakova
    • 1
    Email author
  • L. N. Borovikova
    • 1
  • E. M. Korotkikh
    • 2
  • A. I. Kipper
    • 1
  • O. A. Pisarev
    • 1
    • 2
  1. 1.Institute of High Molecular Weight Compounds, Russian Academy of SciencesSt. PetersburgRussia
  2. 2.Peter the Great Polytechnic UniversitySt. PetersburgRussia

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