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Russian Journal of Physical Chemistry A

, Volume 93, Issue 8, pp 1627–1629 | Cite as

Interaction of Orbitally Ordered Ti3+ Ions with Piperylene in Catalysts for the Polymerization of Diene Compounds

  • V. V. BiktagirovEmail author
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Abstract

The electron paramagnetic resonance in the TiCl4 + triisobutylaluminum catalytic system in an isopentane solution with an excess of an organoaluminum compound has revealed the effect of the removal of orbital ordering upon interaction with piperylene. In this interaction, the EPR spectra of alkylated isolated Ti3+ ions in the ground 3d1 states were detected.

Keywords:

EPR titanium(III) piperylene 

Notes

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Nizhnekamsk Institute for Chemical TechnologyNizhnekamskRussia

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