Advertisement

Russian Journal of Physical Chemistry A

, Volume 93, Issue 6, pp 1049–1053 | Cite as

Effect of a Nitrogen-Containing Base on the Kinetics of Formation of the Zinc–Octa(m-trifluoromethylphenyl)porphyrazine Complex in Benzene

  • O. A. PetrovEmail author
  • G. V. Osipova
  • P. S. Kharlamova
CHEMICAL KINETICS AND CATALYSIS

Abstract

The effect additions of n-butylamine, tert-butylamine, piperidine, and morpholine have on the kinetics of the complexation of zinc acetate with octa(m-trifluoromethylphenyl)porphyrazine in benzene is studied. A possible scheme of the complexation reaction is proposed. It is established that the rate of the reaction slows with the branching of the hydrocarbon chain in the amine, and it grows along with the pKa of the nitrogen-containing base.

Keywords:

porphyrazines nitrogen-containing bases zinc acetate complexation kinetics 

Notes

REFERENCES

  1. 1.
    The Porphyrins Handbook, Applications: Past, Present, and Future, Ed. by K. Kadish, K. Smith, and R. Guilard (Academic, San Diego, San Francisco etc., 2000).Google Scholar
  2. 2.
    T. T. Berezov and B. F. Korovkin, Biological Chemistry (Meditsina, Moscow, 1998) [in Russian].Google Scholar
  3. 3.
    J. Koolman and K.-H. Röhm, Color Atlas of Biochemistry (Thieme, Stuttgart, New York, 2012).Google Scholar
  4. 4.
    O. A. Petrov and B. D. Berezin, Russ. J. Phys. Chem. A 73, 1937 (1999).Google Scholar
  5. 5.
    O. A. Petrov, Russ. J. Coord. Chem. 26, 612 (2000).Google Scholar
  6. 6.
    O. A. Petrov, B. D. Berezin, N. V. Chizhova, and A. S. Semeikin, Russ. J. Coord. Chem. 25, 629 (1999).Google Scholar
  7. 7.
    O. A. Petrov, S. A. Lysova, B. D. Berezin, and N. V. Chizhova, Russ. J. Coord. Chem. 29, 175 (2003).CrossRefGoogle Scholar
  8. 8.
    S. I. Vagin and M. Hanack, Eur. J. Org. Chem., 2859 (2002).Google Scholar
  9. 9.
    Yu. V. Karyakin and I. I. Angelov, Pure Chemical Reagents (Khimiya, Moscow, 1974) [in Russian].Google Scholar
  10. 10.
    L. Tietze and T. Eicher, Reactions and Syntheses: In the Organic Chemistry Laboratory (Wiley, VCH, 2007; Mir, Moscow, 1999).Google Scholar
  11. 11.
    P. Stuzhin, O. Khelevina, and B. Berezin, Phthalocyanines: Properties and Applications (VCH, New York, 1996), Vol. 4, p. 23.Google Scholar
  12. 12.
    P. Stuzhin and O. Khelevina, Coord. Chem. Rev. 147, 41 (1996).CrossRefGoogle Scholar
  13. 13.
    O. A. Petrov, Russ. J. Gen. Chem. 83, 762 (2013).CrossRefGoogle Scholar
  14. 14.
    O. A. Petrov and G. V. Osipova, Russ. J. Gen. Chem. 86, 1912 (2016).CrossRefGoogle Scholar
  15. 15.
    The Handbook of Chemistry and Physics, Ed. by W. M. Haynes (Taylor and Francis, Lodnon, 2013).Google Scholar
  16. 16.
    I. D. Blackburne, A. R. Katritzky, and Y. Takeuchi, Acc. Chem. Res. 8, 300 (1975).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • O. A. Petrov
    • 1
    Email author
  • G. V. Osipova
    • 1
  • P. S. Kharlamova
    • 1
  1. 1.Ivanovo State University of Chemical TechnologyIvanovoRussia

Personalised recommendations