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Russian Journal of Physical Chemistry A

, Volume 93, Issue 6, pp 1206–1208 | Cite as

Calculating the Gibbs Energies of Solvation of 2,2'-Dipyridyl in Nonaqueous Solvents

  • I. A. Kuz’mina
  • M. A. VolkovaEmail author
  • K. I. Kuz’mina
  • N. V. Belova
  • V. A. Sharnin
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Abstract

The Gibbs energies of solvation of 2,2'-dipyridyl (2,2'-Dipy) in methanol (MeOH), acetonitrile (AN), dimethylsulfoxide (DMSO), and N,N-dimethylformamide (DMF) are calculated via quantum chemical modeling. Estimates are made for the contributions from universal and specific types of interaction between the molecules of 2,2'-Dipy and the solvent to the change in the Gibbs energies of solvation of the amine when MeOH is replaced with AN, DMSO, and DMF.

Keywords:

quantum chemical calculations Gibbs energies solvation 2,2'-dipyridyl nonaqueous solvents 

Notes

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • I. A. Kuz’mina
    • 1
  • M. A. Volkova
    • 1
    Email author
  • K. I. Kuz’mina
    • 1
  • N. V. Belova
    • 1
  • V. A. Sharnin
    • 1
  1. 1.Ivanovo State University of Chemistry and TechnologyIvanovoRussia

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