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Russian Journal of Inorganic Chemistry

, Volume 64, Issue 7, pp 882–885 | Cite as

Structure of Monomeric Octahedral d2-Rhenium(V) Monooxo Complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono)] with Oxygen Atoms of Tridentate (O, O, O) and Tetradentate (O, O, O, O) Chelating Ligands

  • V. S. SergienkoEmail author
  • S. B. Strashnova
COORDINATION COMPOUNDS
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Abstract

The structural features of four mononuclear octahedral d2-Re(V) monooxo complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono) with tridentate (O, O, O) and tetradentate (O, O, O, O) chelating ligands are discussed. It is shown that the Re–O(Ltri)trans bonds are elongated, whereas the Re–O(Ltetra)trans bonds are shortened as compared to the Re–O(L)cis bonds.

Keywords

: crystal structure X-ray structural analysis six-coordinated d2-Re monooxo compounds n-dentate (n = 3 4) (O O) and (O O) ligands 

Notes

ACKNOWLEDGMENTS

The author thank Dr. A. V. Churakov (the Kurnakov Institute) for his help in searching data from the Cambridge Structural Database.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia
  2. 2.All-Russia Institute for Scientific and Technical Information, Russian Academy of SciencesMoscowRussia
  3. 3.Peoples’ Friendship University of RussiaMoscowRussia

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