Russian Journal of Inorganic Chemistry

, Volume 64, Issue 7, pp 882–885 | Cite as

Structure of Monomeric Octahedral d2-Rhenium(V) Monooxo Complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono)] with Oxygen Atoms of Tridentate (O, O, O) and Tetradentate (O, O, O, O) Chelating Ligands

  • V. S. SergienkoEmail author
  • S. B. Strashnova


The structural features of four mononuclear octahedral d2-Re(V) monooxo complexes [ReO(Ltri)(Lbi)] and [ReO(Ltetra)(Lmono) with tridentate (O, O, O) and tetradentate (O, O, O, O) chelating ligands are discussed. It is shown that the Re–O(Ltri)trans bonds are elongated, whereas the Re–O(Ltetra)trans bonds are shortened as compared to the Re–O(L)cis bonds.


: crystal structure X-ray structural analysis six-coordinated d2-Re monooxo compounds n-dentate (n = 3 4) (O O) and (O O) ligands 



The author thank Dr. A. V. Churakov (the Kurnakov Institute) for his help in searching data from the Cambridge Structural Database.


  1. 1.
    M. A. Porai-Koshits and E. A. Gilinskaya, Itogi Nauki Tekh.: Kristallokhim., 126 (1966).Google Scholar
  2. 2.
    M. A. Porai-Koshits and L. O. Atovmyan, Koord. Khim. 1, 1271 (1975).Google Scholar
  3. 3.
    F. Griffith and C. Wicing, J. Chem. Soc. A, 379 (1968).Google Scholar
  4. 4.
    M. A. Porai-Koshits, Izv. Yugosl. Kristallogr. Tsentra 9, 19 (1974).Google Scholar
  5. 5.
    M. A. Porai-Koshits and L. O. Atovmyan, The Crystal Chemistry of Molybdenum Coordination Compounds (Nauka, Moscow, 1974) [in Russian].Google Scholar
  6. 6.
    E. M. Shustorovich, M. A. Porai-Koshits, and Yu. A. Buslaev, Coord. Chem. Rev. 17, 1 (1975).CrossRefGoogle Scholar
  7. 7.
    M. A. Porai-Koshits and V. S. Sergienko, Usp. Khim. 59, 86 (1990).CrossRefGoogle Scholar
  8. 8.
    F. H. Allen, Acta Crystallogr., Sect. B 58, 380 (2002).CrossRefGoogle Scholar
  9. 9.
    V. S. Sergienko and A. V. Churakov, Russ. J. Inorg. Chem. 61, 1708 (2016).CrossRefGoogle Scholar
  10. 10.
    V. S. Sergienko, Russ. J. Inorg. Chem. 60, 1723 (2015).CrossRefGoogle Scholar
  11. 11.
    V. S. Sergienko and A. V. Churakov, Crystallogr. Repts. 59, 300 (2014). 1134/S106377451140301711Google Scholar
  12. 12.
    V. S. Sergienko and A. V. Churakov, Crystallogr. Repts. 58, 5 (2013). 1134/S1063774513010112Google Scholar
  13. 13.
    M. Steinborn, M. Suhanji, P. Klufter, Dalton Trans. 42, 5749 (2013).Google Scholar
  14. 14.
    S. Bëlanger and A. L. Beauchamp, Inorg. Chem. 36, 3640 (1997).CrossRefGoogle Scholar
  15. 15.
    C. Redshaw, X. Liu, S. Zhan, et al., Eur. J. Inorg. Chem., 2698 (2008).Google Scholar

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© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia
  2. 2.All-Russia Institute for Scientific and Technical Information, Russian Academy of SciencesMoscowRussia
  3. 3.Peoples’ Friendship University of RussiaMoscowRussia

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