Advertisement

Russian Journal of Inorganic Chemistry

, Volume 63, Issue 6, pp 772–776 | Cite as

Formation of Glycinate Complexes of Iron(II) at Different Ionic Strengths of Solution

  • G. B. Eshova
  • J. A. Davlatshoeva
  • M. M. Rakhimova
  • M. O. Guriev
  • L. V. Kvyatkovskaya
Coordination Compounds
  • 18 Downloads

Abstract

Complexation of iron(II) in aqueous glycine (α-aminoacetic acid) solutions is studied in the pH range 1.0–8.0 at 298.16 K at various ionic strengths (NaClO4). The stability constants of the resulting complexes go down as the ionic strength of the solution increases. The stability constants of the complexes are determined using the experimental “electromotive force of the system versus pH” curves by iterative fitting of the theoretical oxidation function to the experimental one with the Excel program. The correlation between the stability constants of complexes and ionic strength of the solution is also calculated using the Debye–Hückel equation and SigmaPlot 10.0 software. Statistical analysis of the calculated data is performed with P value of 0.95.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Z. N. Yusupov, G. B. Eshova, and S. S. Saidov, Dokl. Akad. Nauk Resp. Tadzh. 51, 620 (2008).Google Scholar
  2. 2.
    L. V. Kvyatkovskaya, G. B. Eshova, D. A. Davlatshoeva, and M. M. Rakhimova, Vestn. TNU, Nos. 1–4 (153), 86 (2014).Google Scholar
  3. 3.
    The Chemist’s Handbook, Eds. by B. P. Nikol’skii and O. N. Grigorov (Khimiya, Moscow, 1965) [in Russian].Google Scholar
  4. 4.
    N. B. Berezin, A. G. Filippova, K. A. Sagdeev, and V. V. Chevela, Butlerov. Soobshch. 5, 39 (2004).Google Scholar
  5. 5.
    M. Beck and I. Nagepal, The Chemistry of Complex Equilibria (Akademiai Kiado, Budapest, 1988).Google Scholar
  6. 6.
    Yu. V. Koryakin and I. I. Angelov, Pure Chemical Substances (Khimiya, Moscow, 1974) [in Russian].Google Scholar
  7. 7.
    G. Charlot, Les methodes de la chimie analytique: Analyse quantitative minerale (Masson, Paris, 1961).Google Scholar
  8. 8.
    E. F. Faizulloev, M. A. Ismailova, Z. N. Yusupov, and M. M. Rakhimova, Vestn. TNU, No. 2(66), 33 (2011).Google Scholar
  9. 9.
    E. F. Faizulloev, M. M. Rakhimova, D. A. Davlatshoeva, et al., Vestn. TNU. Ser. Estestv. Nauk, No. 1/4(153), 66 (2014).Google Scholar
  10. 10.
    V. P. Vasil’ev, Thermodynamic Properties of Electrolyte Solutions (Vysshaya Shkola, Moscow, 1982) [in Russian].Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • G. B. Eshova
    • 1
  • J. A. Davlatshoeva
    • 1
  • M. M. Rakhimova
    • 1
  • M. O. Guriev
    • 1
  • L. V. Kvyatkovskaya
    • 1
  1. 1.Tajik National UniversityDushanbeTajikistan

Personalised recommendations