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Russian Journal of Inorganic Chemistry

, Volume 63, Issue 6, pp 732–735 | Cite as

Synthesis of β-Bromo-Substituted Cu(II) Tetraphenylporphyrinates

  • N. V. Chizhova
  • A. V. Shinkarenko
  • A. V. Zav’yalov
  • N. Zh. Mamardashvili
Synthesis and Properties of Inorganic Compounds
  • 12 Downloads

Abstract

Bromination reactions of Cu(II) 5,10,15,20-tetraphenylporphyrinate with N-bromosuccinimide in chloroform and chloroform–dimethylformamide mixture and complexation of 2-bromo-5,10,15,20-tetraphenylporphyrin and 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin with copper(II) acetate in dimethylformamide have been studied. Mono-, tetra-, and octabromo-substituted Cu(II) porphyrinates have been synthesized. Obtained compounds have been identified by electronic absorption spectroscopy, IR spectroscopy, mass spectrometry, and elemental analysis.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • N. V. Chizhova
    • 1
  • A. V. Shinkarenko
    • 2
  • A. V. Zav’yalov
    • 2
  • N. Zh. Mamardashvili
    • 1
  1. 1.Krestov Institute of Solution ChemistryRussian Academy of SciencesIvanovoRussia
  2. 2.Ivanovo State University of Chemistry and TechnologyIvanovoRussia

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