Russian Journal of Inorganic Chemistry

, Volume 63, Issue 6, pp 776–780 | Cite as

Synthesis and Features of Crystal Structure of Scandium Hexa(isothiocyanato)chromate(III) Complex with Nicotinic Acid

  • E. V. CherkasovaEmail author
  • N. V. Pervukhina
  • N. V. Kuratieva
  • T. G. Cherkasova
Coordination Compounds


A double complex compound with a polymeric cation of composition [Sc2(C6H5NO2)3(C6H4NO2)3][Cr(NCS)6] has been synthesized by the reaction between Sc(NO3)3, K3[Cr(NCS)6], and nicotinic acid (C5H5NCOO) in an aqueous solution and studied by chemical analysis, IR spectroscopy, and X-ray diffraction. Crystals are hexagonal, space group P6322, Z = 2; a = 12.995(2) Å, c = 17.864(3) Å, V = 2612.3(7) Å3, ρcalc = 1.559 g/cm3.


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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • E. V. Cherkasova
    • 1
    Email author
  • N. V. Pervukhina
    • 2
  • N. V. Kuratieva
    • 2
    • 3
  • T. G. Cherkasova
    • 1
  1. 1.Kuzbass State Technical UniversityKemerovoRussia
  2. 2.Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  3. 3.Novosibirsk State UniversityNovosibirskRussia

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