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Kinetics and Catalysis

, Volume 59, Issue 1, pp 70–82 | Cite as

Temperature Hysteresis in the Reaction of Methane Oxidation on a Palladium-Doped Manganese Hexaaluminate Catalyst

  • S. A. Yashnik
  • Z. S. Vinokurov
  • A. V. Salnikov
  • A. V. Ishchenko
  • V. V. Kaichev
  • Z. R. Ismagilov
Article
  • 27 Downloads

Abstract

A study of the Pd-containing catalyst based on manganese hexaaluminate by X-ray diffraction analysis, transmission electron microscopy, thermo-programmed reduction with hydrogen, and thermoprogrammed oxidation showed the hysteresis manifested itself in a difference between the temperature dependences of its catalytic activity in the oxidation of methane under the conditions of sample heating or cooling is related to the decomposition of PdO to metallic palladium at temperatures higher than 700–800°C and the subsequent formation of PdO nanoparticles, which are localized on the surface of metallic Pd (30–50 nm) in the form of polycrystalline films with a thickness of 2–5 nm, at temperatures lower than 600–700°C. A near-surface oxide film is formed under the conditions of cooling in oxygen-containing atmospheres, including in the presence of methane. The value of the hysteresis depends on the heat treatment temperature of the catalyst, and it reaches a maximum on the catalysts calcined at 900 and 1000°C.

Keywords

manganese hexaaluminate palladium doping methane oxidation thermal hysteresis TPR-O2 in situ XRD analysis 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • S. A. Yashnik
    • 1
  • Z. S. Vinokurov
    • 1
  • A. V. Salnikov
    • 1
  • A. V. Ishchenko
    • 1
  • V. V. Kaichev
    • 1
  • Z. R. Ismagilov
    • 1
    • 2
  1. 1.Boreskov Institute of Catalysis, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Institute of Coal Chemistry and Chemical Materials Science, Siberian BranchRussian Academy of SciencesKemerovoRussia

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