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Kinetics and Catalysis

, Volume 59, Issue 1, pp 11–16 | Cite as

Measurement of the Rate Constant of a Reaction of Chlorine Atoms with CH3Br in a Temperature Range of 298–358 K Using the Resonance Fluorescence of Chlorine Atoms

  • I. K. Larin
  • A. I. Spasskii
  • E. M. Trofimova
  • N. G. Proncheva
Article

Abstract

The rate constant of the reaction of chlorine atoms with CH3Br was measured in a temperature range of 298–358 K using the resonance fluorescence of chlorine atoms. The possible role of this reaction in atmospheric chemistry and fire extinguishing was discussed. It was found that this reaction is homogeneous in contrast to the previously studied reaction of chlorine atoms with CH3I, with occurs at the reactor surface.

Keywords

atmospheric chemistry chlorine reaction with CH3Br resonance fluorescence 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • I. K. Larin
    • 1
  • A. I. Spasskii
    • 1
  • E. M. Trofimova
    • 1
  • N. G. Proncheva
    • 2
  1. 1.Talrose Institute of Energy Problems of Chemical PhysicsRussian Academy of SciencesMoscowRussia
  2. 2.Keldysh Institute of Applied MathematicsRussian Academy of SciencesMoscowRussia

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