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Journal of Structural Chemistry

, Volume 60, Issue 6, pp 967–971 | Cite as

Synthesis, Structure and Emission Properties of [Cu22-I)2L4] Complex Based on 2-(Methylthio)Pyrazine

  • A. V. Artem’evEmail author
  • A. S. Beresin
  • I. Yu. Bagryanskaya
Article
  • 6 Downloads

Abstract

Reaction of 2-(methylthio)pyrazine (L) with CuI (MeCN, r.t.) results in formation of iodide-bridged complex [Cu22-I)2L4], wherein Cu⋯Cu contact of 2.6351(4) Å is observed. The each metal atom of the [Cu22-I)2] core is coordinated by the two ligands via 4-pyrazyl nitrogen atoms. In the solid state at room temperature, the complex obtained emits an orange photoluminescence (λmax = 600 nm) with the average lifetime of 1.66 μs and quantum yield of 17%.

Keywords

copper(I) pyrazines sulfide ligands photoluminescence crystal structure 

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Notes

Acknowledgments

The authors are grateful to the Multi-Access Chemical Service Center SB RAS for single crystal XRD analysis.

References

  1. 1.
    R. Peng, M. Li, and D. Li. Coord. Chem. Rev., 2010, 254, 1.CrossRefGoogle Scholar
  2. 2.
    E. Cariati, E. Lucenti, C. Botta, U. Giovanella, D. Marinottoc, and S. Righetto. Coord. Chem. Rev., 2016, 306, 566.CrossRefGoogle Scholar
  3. 3.
    M. S. Lazorski and F. N. Castellano. Polyhedron, 2014, 82, 57.CrossRefGoogle Scholar
  4. 4.
    G.-N. Liu, R.-Y. Zhao, R.-D. Xu, X. Zhang, X.-N. Tang, Q.-J. Dan, Y.-W. Wei, Y.-Y. Tu, Q.-B. Bo, and C. Li. Cryst. Growth Des., 2018, 18, 5441.CrossRefGoogle Scholar
  5. 5.
    H. Araki, K. Tsuge, Y. Sasaki, S. Ishizaka, and N. Kitamura. Inorg. Chem., 2005, 44, 9667.CrossRefGoogle Scholar
  6. 6.
    C. Näther, I. Jeß, N. Lehnert, and D. Hinz-Hübner. Solid State Sci., 2003, J, 1343.Google Scholar
  7. 7.
    B. Roßenbeck and W. S. Sheldrick. Z. Naturforsch., 1999, 54b, 1510.CrossRefGoogle Scholar
  8. 8.
    C. Näther, J. Greve, and I. Jeß. Solid State Sci., 2002, 4, 813.CrossRefGoogle Scholar
  9. 9.
    C. Näther, M. Wriedt, and I. Jess. Inorg. Chem., 2003, 42, 2391.CrossRefGoogle Scholar
  10. 10.
    I. Jeß, P. Taborsky, J. Pospíšil, and C. Näther. Dalton Trans., 2007, 2263.Google Scholar
  11. 11.
    I. L. Malaestean, V. C. Kravtsov, J. Lipkowski, E. Cariati, S. Righetto, D. Marinotto, A. Forni, and M. S. Fonari, Inorg. Chem., 2017, 56, 5141.CrossRefGoogle Scholar
  12. 12.
    N. Kitada and T. Ishida. Cryst Eng Comm, 2014, 16, 8035.CrossRefGoogle Scholar
  13. 13.
    X. Zhang, W. Liu, G. Z. Wei, D. Banerjee, Z. Hu, J and Li. J. Am. Chem. Soc., 2014, 136, 14230.CrossRefGoogle Scholar
  14. 14.
    W. Liu, K. Zhu, S. J. Teat, B. J. Deibert, W. Yuan, and J. Li. J. Mater. Chem. C, 2017, J, 5962.Google Scholar
  15. 15.
    J. Conesa-Egea, J. Gallardo-Martínez, S. Delgado, J. I. Martínez, J. Gonzalez-Platas, V. Fernández-Moreira, U. R. Rodríguez-Mendoza, P. Ocón, F. Zamora, and P. Amo-Ochoa. Small, 2017, 13, 1700965.CrossRefGoogle Scholar
  16. 16.
    N. Armaroli, G. Accorsi, F. Cardinali, and A. Listorti. In: Photochemistry and Photophysics of Coordination Compounds I / Eds. V. Balzani and S. Campagna. Springer: Heidelberg, 2007, Vol. 280, 69–115.CrossRefGoogle Scholar
  17. 17.
    P. D. Harvey and M. Knorr. J. Clust. Sci., 2015, 26, 411.CrossRefGoogle Scholar
  18. 18.
    G. M. Sheldrick. Acta Crystallogr., Sect. C: Struct. Chem., 2015, 71, 3.CrossRefGoogle Scholar
  19. 19.
    SADABS, v. 2008-1. Bruker AXS, Madison, WI, USA, 2008.Google Scholar
  20. 20.
    A. Bondi. J. Phys. Chem., 1964, 68, 441.CrossRefGoogle Scholar
  21. 21.
    L. Yang, D. R. Powell, and R. P. Houser. Dalton Trans., 2007, 955.Google Scholar
  22. 22.
    Yu. I. Slyvka, B. R. Ardan, and M. G. Mys'kiv. J. Struct. Chem., 2018, 59, 388.CrossRefGoogle Scholar
  23. 23.
    A. Aguirrechu-Comeron, R. Hernández-Molina, and J. González-Platas. J. Struct. Chem., 2018, 59, 943.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Inc. 2019

Authors and Affiliations

  • A. V. Artem’ev
    • 1
    • 2
    Email author
  • A. S. Beresin
    • 1
    • 2
  • I. Yu. Bagryanskaya
    • 2
    • 3
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia
  3. 3.Vorozhtsov Institute of Organic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia

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