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Journal of Structural Chemistry

, Volume 60, Issue 6, pp 855–881 | Cite as

Homo- and Heteronuclear Architectures of Polynuclear Complexes Containing Anions of Substituted Malonic Acids: Synthetic Approaches and Analysis of Molecular and Crystal Structures

  • E. S. BazhinaEmail author
  • N. V. Gogoleva
  • E. N. Zorina-Tikhonova
  • M. A. Kiskin
  • A. A. Sidorov
  • I. L. Eremenko
Article
  • 27 Downloads

Abstract

The review summarizes the data obtained in the studies of transition metal complexes (VIVO, CoII, NiII, CuII, ZnII) with anions of substituted malonic acids, which are not only coordination polymers but also compounds with a discrete molecular structure. The influence of malonic acid substituents and the nature of metal ions (alkali, alkaline earth, and transition metals) on the formation of molecular and polymeric systems is discussed. The crystal structures of recently described heterometallic coordination polymers are analyzed.

Keywords

oxidovanadium(IV) copper(II) cobalt(II) nickel(II) zinc(II) lithium barium sodium potassium malonic acid hydroxymalonate complexes heterometallic complexes coordination polymers crystal structure 

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Copyright information

© Pleiades Publishing, Inc. 2019

Authors and Affiliations

  • E. S. Bazhina
    • 1
    Email author
  • N. V. Gogoleva
    • 1
  • E. N. Zorina-Tikhonova
    • 1
  • M. A. Kiskin
    • 1
  • A. A. Sidorov
    • 1
  • I. L. Eremenko
    • 1
  1. 1.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia

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