Advertisement

Journal of Structural Chemistry

, Volume 60, Issue 5, pp 823–829 | Cite as

Crystal Structure of Coordination Polymers Based on Scandium and 2,5-Pyrazinedicarboxylic Acid

  • M. O. Barsukova
  • A. A. Sapianik
  • D. G. Samsonenko
  • V. P. FedinEmail author
Article
  • 2 Downloads

Abstract

In the interaction of scandium chloride hexahydrate and 2,5-pyrazinedicarboxylic acid (H2pzc) dihydrate in different solvent mixtures two novel coordination polymers are obtained under solvothermal conditions: [Sc2(dmf)2(H2O)2(pzc)3] (1) and [Sc2(H2O)2(pzc)3]·2CH3CN·H2O (2) (dmf is N,N-dimethylformamide). Crystal structures of compounds 1 and 2 are determined by single crystal X-ray diffraction and supported by elemental and thermogravimetric data and IR spectroscopy. The phase purity of the samples prepared is confirmed by powder X-ray diffraction. It is shown that the coordination environment of the scandium cation and the 2,5-pyrazinedicarboxylate ligand denticity change depending on the composition of a solvent mixture. Compound 1 has a layered structure while in the structure of 2 there is a three-dimensional framework.

Keywords

scandium coordination polymers heterocyclic ligands X-ray crystallography analysis 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    D. N. Dybtsev, A. A. Sapianik, and V. P. Fedin. Mendeleev Commun., 2017, 4, 321.CrossRefGoogle Scholar
  2. 2.
    A. A. Sapianik, E. E. Semenenko, D. G. Samsonenko, D. N. Dybtsev, and V. P. Fedin. J. Struct. Chem., 2018, 59, 487.CrossRefGoogle Scholar
  3. 3.
    L. Jiao, Y. Wang, H.-L. Jiang, and Q. Xu. Adv. Mater., 2018, 30, 1703663.CrossRefGoogle Scholar
  4. 4.
    M. Cheng, C. Lai, Y. Liu, G. Zeng, D. Huang, C. Zhang, L. Qin, L. Hu, C. Zhou, and W. Xiong. Cood. Chem. Rev., 2018, 368, 80.CrossRefGoogle Scholar
  5. 5.
    J.-R. Li, J. Sculley, and H.-C. Zhou. Chem. Rev., 2012, 112, 869.CrossRefGoogle Scholar
  6. 6.
    H. Li, K. Wang, Y. Sun, C. T. Lollar, J. Li, and H.-C. Zhou. Mater. Today, 2018, 21, 108.CrossRefGoogle Scholar
  7. 7.
    E. S. Sanz-Perez, C. R. Murdock, S. A. Didas, and C. W. Jones. Chem. Rev., 2016, 116, 11840.CrossRefGoogle Scholar
  8. 8.
    G. Minguez Espallargas and E. Coronado. Chem. Soc. Rev., 2018, 47, 533.CrossRefGoogle Scholar
  9. 9.
    F. Maya, C. Palomino Cabello, R. M. Frizzarin, J. M. Estela, G. Turnes Palomino, and V. Cerda. TrAC Trend. Anal. Chem., 2017, 90, 142.CrossRefGoogle Scholar
  10. 10.
    Y. Zhang, S. Yuan, G. Day, X. Wang, X. Yang, and H.-C. Zhou. Coord. Chem. Rev., 2018, 354, 28.CrossRefGoogle Scholar
  11. 11.
    W. P. Lustig, S. Mukherjee, N. D. Rudd, A. V. Desai, J. Li, and S. K. Gosh. Chem. Soc. Rev., 2017, 46, 3242.CrossRefGoogle Scholar
  12. 12.
    S. Yuan, L. Feng, K. Wang, J. Pang, M. Bosch, C. Lollar, Y. Sun, J. Qin, X. Yang, P. Zhang, Q. Wang, L. Zou, Y. Zhang, Y. Fang, J. Li, and H.-C. Zhou. Adv. Mater., 2018, 30, 1704303.CrossRefGoogle Scholar
  13. 13.
    M. O. Barsukova, S. A. Sapchenko, D. N. Dybtsev, and V. P. Fedin. Russ. Chem. Rev., 2018, 87, 1139.CrossRefGoogle Scholar
  14. 14.
    A. M. Cheplakova, I. S. Fedoseev, P. V. Dorovatovskii, V. A. Lazarenko, Ya. V. Zubavichus, V. N. Khrustalev, and V. P. Fedin. J. Struct. Chem., 2018, 59, 494.CrossRefGoogle Scholar
  15. 15.
    M. O. Barsukova, D. G. Samsonenko, A. A. Sapianik, S. A. Sapchenko, and V. P. Fedin. Polyhedron, 2018, 144, 219.CrossRefGoogle Scholar
  16. 16.
    CrysAlisPro 1.171.38.41. Rigaku Oxford Diffraction, 2015.Google Scholar
  17. 17.
    G. M. Sheldrick. Acta Crystallogr. A, 2015, 71, 3.CrossRefGoogle Scholar
  18. 18.
    G. M. Sheldrick. Acta Crystallogr. C, 2015, 71, 3.CrossRefGoogle Scholar
  19. 19.
    A. L. Spek. Acta Crystallogr. D, 2009, 65, 148.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • M. O. Barsukova
    • 1
    • 2
  • A. A. Sapianik
    • 1
    • 2
  • D. G. Samsonenko
    • 1
    • 2
  • V. P. Fedin
    • 1
    • 2
    Email author
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia

Personalised recommendations