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Journal of Structural Chemistry

, Volume 60, Issue 5, pp 815–822 | Cite as

Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements

  • P. A. Demakov
  • S. A. Sapchenko
  • D. G. Samsonenko
  • D. N. Dybtsev
  • V. P. FedinEmail author
Article
  • 2 Downloads

Abstract

By a reaction of lanthanide nitrates with trans-1,4-cyclohexane dicarboxylic acid H2chdc in an aqueous medium new coordination polymers with the composition [Ln2(H2O)4(chdc)3] (Ln = Ce (1), Sm (2), Eu (3), Gd (4)) are obtained. Crystallization conditions are optimized with the use of a hexamine-based pH buffer. Compound 1 is additionally characterized by powder X-ray diffraction, elemental and thermogravimetric analyses, and IR spectroscopy. The structure of the obtained compounds is determined by single crystal X-ray diffraction. In a series of isostructural three-dimensional frameworks [Ln2(H2O)4(chdc)3] (Ln = La—Eu, except Pm) a regular change in the structural features is analyzed. The [Gd2(H2O)4(chdc)3] compound has a similar composition but the topology of the three-dimensional network differs from that of the previous ones due to a decrease in the coordination number of metal centers. Heavier lanthanides, starting from Tb3+, and also yttrium(III) do not form compounds with the mentioned composition under similar reaction conditions.

Keywords

lanthanides coordination polymers metal-organic frameworks single crystal X-ray diffraction analysis lanthanide compression 

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References

  1. 1.
    D. Aulakh, J. R. Varghese, and M. Wriedt. Inorg. Chem., 2015, 54, 8679.CrossRefGoogle Scholar
  2. 2.
    Y. Lo, C. H. Lam, C.-W. Chang, A.-C. Yang, and D.-Y. Kang. RSC Adv., 2016, 6, 89148.CrossRefGoogle Scholar
  3. 3.
    T. Tanasaro, K. Adpakpang, S. Ittisanronnachai, K. Faungnawakij, T. Butburee, S. Wannapaiboon, M. Ogawa, and S. Bureekaew. Cryst. Growth Des., 2018, 18, 16.CrossRefGoogle Scholar
  4. 4.
    T. K. Koltunova, D. G. Samsonenko, D. N. Dybtsev, and V. P. Fedin. J. Struct. Chem., 2017, 58, 1048.CrossRefGoogle Scholar
  5. 5.
    M. O. Barsukova, S. A. Sapchenko, D. N. Dybtsev, and V. P. Fedin. Russ. Chem. Rev., 2018, 87, 1139.CrossRefGoogle Scholar
  6. 6.
    P. A. Demakov, S. A. Sapchenko, D. G. Samsonenko, D. N. Dybtsev, and V. P. Fedin. Russ. Chem. Bull. (Int. Ed.), 2018, 67, 490.CrossRefGoogle Scholar
  7. 7.
    M. Yu, S.-X. Liu, L.-H. Xie, R.-G. Cao, and Y.-H. Ren. Acta Cryst. Sec. E, 2007, 63, 1889.CrossRefGoogle Scholar
  8. 8.
    Y.-J. Kim. and D.-Y. Jung. Chem. Commun., 2002, 8, 908.CrossRefGoogle Scholar
  9. 9.
    G. Tian, G. Zhu, B.-L. Su, and S. Qiu. J. Mater. Sci., 2009, 44, 6576.CrossRefGoogle Scholar
  10. 10.
    J. Lu, W. Bi, and R. Cao. CrystEngComm, 2009, 11, 2248.CrossRefGoogle Scholar
  11. 11.
    K. P. Rao, A. Thirumurugan, and C. N. R. Rao. Chem.-Eur. J., 2007, 13, 3193.CrossRefGoogle Scholar
  12. 12.
    J. Lu, W.-H. Bi, F.-X. Xiao, S. R. Batten, and R. Cao. Chem.-Asian J., 2008, 3, 542.CrossRefGoogle Scholar
  13. 13.
    CrysAlisPro 1.171.38.41. Rigaku Oxford Diffraction, 2015.Google Scholar
  14. 14.
    G. M. Sheldrick. Acta Crystallogr., 2015, A71, 3–8.Google Scholar
  15. 15.
    G. M. Sheldrick. Acta Crystallogr., 2015, C71, 3–8.Google Scholar
  16. 16.
    Y. Guo, J. Zhang, L.-Z. Dong, Y. Xu, W. Han, M. Fang, H.-K. Liu, Y. Wu, and Y.-Q. Lan. Chem.-Eur. J., 2017, 23, 15518.CrossRefGoogle Scholar
  17. 17.
    G. Férey, C. Mellot-Draznieks, C. Serre, F. Millange, J. Dutour, S. Surblé, and I. Margiolaki. Science, 2005, 309, 2040.CrossRefGoogle Scholar
  18. 18.
    G. Zahn, P. Zerner, J. Lippke, F. L. Kempf, S. Lilienthal, C. A. Schröder, A. M. Schneider, and P. Behrens. CrystEngComm., 2014, 16, 9198.CrossRefGoogle Scholar
  19. 19.
    Z. Hu, I. Castano, S. Wang, Y. Wang, Y. Peng, Y. Qian, C. Chi, X. Wang, and D. Zhao. Cryst. Growth Des., 2016, 16, 2295.CrossRefGoogle Scholar
  20. 20.
    R.-Z. Zhang, Y.-Q. Huang, W. Zhang, and J.-M. Yang. CrystEngComm., 2018, 20, 5672.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • P. A. Demakov
    • 1
    • 2
  • S. A. Sapchenko
    • 1
    • 2
  • D. G. Samsonenko
    • 1
    • 2
  • D. N. Dybtsev
    • 1
    • 2
  • V. P. Fedin
    • 1
    • 2
    Email author
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia

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