Journal of Structural Chemistry

, Volume 60, Issue 5, pp 815–822 | Cite as

Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements

  • P. A. Demakov
  • S. A. Sapchenko
  • D. G. Samsonenko
  • D. N. Dybtsev
  • V. P. FedinEmail author


By a reaction of lanthanide nitrates with trans-1,4-cyclohexane dicarboxylic acid H2chdc in an aqueous medium new coordination polymers with the composition [Ln2(H2O)4(chdc)3] (Ln = Ce (1), Sm (2), Eu (3), Gd (4)) are obtained. Crystallization conditions are optimized with the use of a hexamine-based pH buffer. Compound 1 is additionally characterized by powder X-ray diffraction, elemental and thermogravimetric analyses, and IR spectroscopy. The structure of the obtained compounds is determined by single crystal X-ray diffraction. In a series of isostructural three-dimensional frameworks [Ln2(H2O)4(chdc)3] (Ln = La—Eu, except Pm) a regular change in the structural features is analyzed. The [Gd2(H2O)4(chdc)3] compound has a similar composition but the topology of the three-dimensional network differs from that of the previous ones due to a decrease in the coordination number of metal centers. Heavier lanthanides, starting from Tb3+, and also yttrium(III) do not form compounds with the mentioned composition under similar reaction conditions.


lanthanides coordination polymers metal-organic frameworks single crystal X-ray diffraction analysis lanthanide compression 


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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • P. A. Demakov
    • 1
    • 2
  • S. A. Sapchenko
    • 1
    • 2
  • D. G. Samsonenko
    • 1
    • 2
  • D. N. Dybtsev
    • 1
    • 2
  • V. P. Fedin
    • 1
    • 2
    Email author
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia

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