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Journal of Structural Chemistry

, Volume 60, Issue 5, pp 810–814 | Cite as

Synthesis and Crystal Structure of Nickel(II) and Zinc(II) Complexes with O-Propylxanthate and N, N, N′,N′-Tetramethylethylenediamine

  • A. M. QadirEmail author
  • N. Dege
Article
  • 5 Downloads

Abstract

The reaction of NiCl2·6H2O or Zn(CH3CO2)·2H2O with potassium O-propylxanthate (KS2COC3H7) and N, N, N′,N′-tetramethylethylenediamine (tmeda) affords monomeric complexes of the formula [M(S2COC3H7)2(tmeda)] (M = Ni(II) 1; Zn(II) 2). Both complexes are characterized by single crystal X-ray diffraction, elemental analysis, IR spectroscopy. Complexes 1 and 2 crystalize in monoclinic P21/c and I2/a space groups, respectively. Each metal center is ligated by four S atoms from xanthate ligands and two N atoms from tmeda in a distorted octahedral geometry.

Keywords

xanthate complex X-ray Zn(II) synthesis 

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Department of Chemistry, College of ScienceSalahaddin UniversityErbilIraq
  2. 2.Science Faculty, Department of PhysicsUniversity of OndokuzmayısSamsunTurkey

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