Journal of Structural Chemistry

, Volume 60, Issue 5, pp 803–809 | Cite as

Crystal Structure And Luminescent Property of a New Two-Dimensional Polymer Based on 1,4-Bis(4-(Imidazole-1-yl)Benzyl)Piperazine

  • C. ZhangEmail author
  • J. -Q. Tao
  • J. Wang


A two-dimensional Zn(II) complex [Zn(BIBP)(TBIP)]n (1) (BIBP = 1,4-bis(4-(imidazole-1-yl)benzyl)piperazine, H2TBIP = 5-tert-butyl isophthalic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. The single crystal X-ray diffraction analysis reveals that complex 1 is an achiral two-dimensional layer based on 1D left- and right-handed helical [Zn(BIBP)] n 2 chains, which are linked by C—H⋯O hydrogen bonds to form a three-dimensional supramolecular framework. Moreover, complex 1 exhibits an emission band at 393 nm (λex = 244 nm).


coordination polymer two-dimensional layer 1,4-bis(4-(imidazole-1-yl)benzyl)piperazine 5-tert-butyl isophthalic acid luminescent property 


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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.School of Chemistry and Environmental EngineeringYancheng Teachers UniversityYanchengP. R. China

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