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Journal of Structural Chemistry

, Volume 60, Issue 5, pp 796–802 | Cite as

Crystal Structure of (NH4)2VO(SO4)2·H2O

  • A. P. Tyutyunnik
  • V. N. Krasil’nikov
  • I. V. BaklanovaEmail author
  • R. F. Samigullina
Article
  • 3 Downloads

Abstract

Ammonium vanadate(IV) oxosulfate with the composition (NH4)2VO(SO4)2·H2O is synthesized and its crystal structure is investigated. It is found that the compound crystallizes in monoclinic crystal symmetry (space group P21, Z = 2) with lattice parameters: \(a = 4.65037\left( 4 \right)\;\acute{\mathring{\mathrm{A}}} \), \(b = 10.9870\left( 1 \right)\;\acute{\mathring{\mathrm{A}}} \), \(c = 9.5666\left( 1 \right)\;\acute{\mathring{\mathrm{A}}} \), β = 98.6273(5)°, \(V = 483.260\left( 8 \right){\acute{\mathring{\mathrm{A}}} ^3}\), Z = 2. The crystal structure of the compound is composed of VO5H2O octahedra sharing vertices of bridging groups SO4 and making infinite chains parallel to the a axis. In the vertex of the VO5H2O octahedron there is a short terminal vanadyl bond V4+=O with a length of \(1.564\left( 7 \right)\;\acute{\mathring{\mathrm{A}}} \). A water molecule is trans positioned to this group at a distance of \(2.355\left( 6 \right)\;\acute{\mathring{\mathrm{A}}} \). The chains are linked with each other by (NH4)+ ions.

Keywords

complex compounds of vanadium(IV) oxosulfatovanadates synthesis crystal structure 

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. P. Tyutyunnik
    • 1
  • V. N. Krasil’nikov
    • 1
  • I. V. Baklanova
    • 1
    Email author
  • R. F. Samigullina
    • 1
  1. 1.Institute of Solid State Chemistry, Ural BranchRussian Academy of SciencesEkaterinburgRussia

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