Advertisement

Journal of Structural Chemistry

, Volume 60, Issue 5, pp 789–795 | Cite as

A Study of the Crystal Structure of SmCaCo1−xFexO4−δ and Sm0.9Ca1.1Fe1−yCoyO4−δ Solid Solutions

  • A. P. GalaydaEmail author
  • N. E. Volkova
  • A. A. Startseva
  • L. Ya. Gavrilova
  • V. A. Cherepanov
Article
  • 2 Downloads

Abstract

Complex oxides with general compositions SmCaCo1−xFexO4−δ and Sm0.9Ca1.1Fe1−yCoyCO4−δ are synthesized using the glycerol-nitrate technique at 1100 °C in air. By powder X-ray diffraction it is determined that SmCaCo1−xFexO4−δ solid solutions exist in a composition range 0 ≤ x ≤ 0.3 and Sm0.9Ca1.1Fe1yCoyO4−δ solid solutions exist in a composition range 0 ≤ y ≤ 0.7. The samples with high concentrations of cobalt ions are found to crystallize in the tetragonal unit cell (space group I4/mmm), whereas the solid solutions enriched with iron ions have the orthorhombic structure (space group Bmab). For all single phase samples the unit cell parameters and volume and the structural parameters (atomic coordinates and bond lengths) are calculated by the full-profile Rietveld method.

Keywords

complex oxides Ruddlesden-Popper phases ferrites cobaltites powder X-ray diffraction analysis crystal structure 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    A. Petric, P. Huang, and F. Tietz. Solid State Ion., 2000, 135, 719.CrossRefGoogle Scholar
  2. 2.
    S. Ya. Istomin and E. V. Antipov. Russ. Chem. Rev., 2013, 82, 686.CrossRefGoogle Scholar
  3. 3.
    J. Dailly, S. Fourcade, A. Largeteau, F. Mauvy, J. C. Grenier, and M. Marrony. Electrochim. Acta, 2010, 55, 5847.CrossRefGoogle Scholar
  4. 4.
    Sh. I. Elkalashy, A. R. Gilev, T. V. Aksenova, A. S. Urusova, and V. A. Cherepanov. Solid State Ion., 2018, 316, 85.CrossRefGoogle Scholar
  5. 5.
    M. Al Daroukh, V. V. Vashook, H. Ullmann, F. Tietz, and I. Arual Raj. Solid State Ion., 2003, 158, 141.CrossRefGoogle Scholar
  6. 6.
    V. V. Kharton, E. V. Tsipis, A. A. Yaremchenko, and J. R. Frade. Solid State Ion., 2004, 166, 327.CrossRefGoogle Scholar
  7. 7.
    F. Zhao, X. Wang, Z. Wang, R. Peng, and C. Xia. Solid State Ion., 2008, 179, 1450.CrossRefGoogle Scholar
  8. 8.
    A. N. Petrov, V. A. Cherepanov, A. Yu. Zuyev, and V. M. Zhukovsky. J. Solid State Chem., 1988, 77, 1.CrossRefGoogle Scholar
  9. 9.
    H. Taguchi, H. Kido, and T. Tabata. Physica B, 2004, 344, 271.CrossRefGoogle Scholar
  10. 10.
    H. Taguchi, K. Nakade, and K. Hirota. Mater. Res. Bull., 2007, 42, 649.CrossRefGoogle Scholar
  11. 11.
    W. Wong-Ng, W. Laws, K. R. Talley, Q. Huang, Y. Yan, J. Martin, and J. A. Kaduk. J. Solid State Chem., 2014, 215, 128.CrossRefGoogle Scholar
  12. 12.
    W. Wong-Ng, W. Laws, S. H. Lapidus, L. Ribaud, and J. A. Kaduk. Solid State Sci., 2017, 72, 47.CrossRefGoogle Scholar
  13. 13.
    W. Wong-Ng, W. Laws, and J. A. Kaduk. Solid State Sci., 2016, 58, 105.CrossRefGoogle Scholar
  14. 14.
    W. Wong-Ng, W. Laws, S. H. Lapidus, and J. A. Kaduk. Solid State Sci., 2015, 48, 31.CrossRefGoogle Scholar
  15. 15.
    N. E. Volkova, A. V. Maklakova, L. Ya. Gavrilova, and V. A. Cherepanov. Eur. J. Inorg. Chem., 2017, 3285.Google Scholar
  16. 16.
    O. A. Shlyakhtin, G. N. Mazo, M. S. Kaluzhskikh, D. A. Komissarenko, A. S. Loktev, and A. G. Dedov. Mater. Lett., 2012, 75, 20.CrossRefGoogle Scholar
  17. 17.
    V. A. Cherepanov, L. Ya. Gavrilova, L. Yu. Barkhatova, V. I. Voronin, M. V. Trifonova, and O. A. Bukhner. Ionics, 1998, 4, 309.CrossRefGoogle Scholar
  18. 18.
    A. P. Galayda, N. E. Volkova, L. Ya. Gavrilova, K. G. Balymov, and V. A. Cherepanov. J. Alloys Compd., 2017, 718, 288.CrossRefGoogle Scholar
  19. 19.
    G. J. Thorogood, P.-Y. Orain, M. Ouvry, B. Piriou, T. Tedesco, K. S. Wallwork, J. Herrmann, and M. James. J. Solid State Chem., 2011, 13, 2113.Google Scholar
  20. 20.
    L.-W. Tai, M. M. Nasrallah, H. U. Anderson, D. M. Sparlin, and S. R. Sehlin. Solid State Ion., 1995, 76, 259.CrossRefGoogle Scholar
  21. 21.
    S. Ki-Woog and L. Ki-Tae. Ceram. Int., 2011, 37, 573.CrossRefGoogle Scholar
  22. 22.
    K. T. Lee and A. Manthiram. Solid State Ion., 2005, 176, 1521.CrossRefGoogle Scholar
  23. 23.
    A. Petric, P. Huang, and F. Tietz. Solid State Ion., 2000, 135, 719.CrossRefGoogle Scholar
  24. 24.
    M. M. Nguyen-Trut-Dinh, M. Vlasse, M. Perrin, and G. Le Flem. J. Solid State Chem., 1980, 32, 1.CrossRefGoogle Scholar
  25. 25.
    R. D. Shannon. Acta Crystallogr., 1976, 32, 751.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. P. Galayda
    • 1
    Email author
  • N. E. Volkova
    • 1
  • A. A. Startseva
    • 1
  • L. Ya. Gavrilova
    • 1
  • V. A. Cherepanov
    • 1
  1. 1.Institute of Natural Sciences and MathematicsUral Federal UniversityEkaterinburgRussia

Personalised recommendations